3-methoximinopropionic esters and fungicides containing them

ABSTRACT

3-Methoximinopropionic esters of the formula ##STR1## where the radicals R (m=1 to 5) are each hydrogen, halogen, cyano, nitro, alkyl, cycloalkyl, alkenyl, alkoxy, haloalkyl, haloalkoxy, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy, unsubstituted or substituted benzyl or unsubstituted or substituted benzyloxy, or the group ##STR2## is naphthyl, and X is methyleneoxy, oxymethylene, ethylene, ethenylene, thiomethylene or oxygen, and fungicides containing these compounds.

The present invention relates to novel 3-methoximinopropionic esters and fungicides containing them. It is known that oxime ether derivatives, for example methyl 2-(2-methylbenzyloxy)-phenylglyoxylateO-methyloxime, can be used as fungicides (European Patent 253,213). However, their action is often inadequate for some indications.

We have found that novel 3-methoximinopropionic esters of the general formula I ##STR3## where the radicals R (m=1 to 5) are identical or different and are each hydrogen, halogen, cyano, nitro, C₁ -C₁₅ -alkyl, C₃ -C₆ -cycloalkyl, C₃ -C₆ -alkenyl, C₁ -C₄ -alkoxy, C₁ -or C₂ -haloalkyl, C₁ - or C₂ -haloalkoxy, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy, unsubstituted or substituted benzyl or unsubstituted or substituted benzyloxy, or the group ##STR4## is α-naphthyl or β-naphthyl, and X is methyleneoxy, oxymethylene, ethylene, ethenylene, thiomethylene or oxygen, have an excellent fungicidal action which is better than that of the known ether derivatives.

The radicals stated in the general formula I have, for example, the following meanings: R (m=1 to 5) may be, for example: hydrogen, halogen (e.g. fluorine, chlorine, bromine or iodine), cyano, nitro, C₁ -C₁₅ -alkyl, (e.g. methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, pentyl, hexyl, heptyl, octyl, nonyl or decyl), C₃ -C₆ -cycloalkyl (e.g. cyclopropyl, cyclopentyl or cyclohexyl), C₃ -C₆ -alkenyl (e.g. 1-propenyl or 2-propenyl), C₁ -C₄ -alkoxy (e.g. methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy or tert-butoxy), C₁ - or C₂ -haloalkyl (e.g. difluoromethyl, trifluoromethyl, chloromethyl, dichloromethyl, trichloromethyl or pentafluoroethyl), C₁ - or C₂ -haloalkoxy (e.g. trifluoromethoxy, difluoromethoxy, tetrafluoroethoxy or pentafluoroethoxy), unsubstituted or substituted phenyl (e.g. phenyl, C₁ -C₄ -alkylphenyl or halophenyl), unsubstituted or substituted phenoxy (e.g. phenoxy, C₁ -C₄ -alkylphenoxy or halophenoxy), unsubstituted or substituted benzyl (e.g. benzyl or halobenzyl) or unsubstituted or substituted benzyloxy (e.g. benzyloxy, halobenzyloxy or C₁ -C₄ -alkylbenzyloxy). Furthermore, the group ##STR5## may be α-naphthyl or β-naphthyl.

X is preferably --CH₂ O--, --OCH₂ --, --CH₂ --CH₂ --, --CH═CH-- or an --SCH₂ chain or is O.

m is 1, 2, 3, 4 or 5, preferably from 1 to 3.

Because of the C═N double bond, the novel compounds of the general formula I may occur both as E isomers and as X isomers. Both the individual isomeric compounds and mixtures thereof form subjects of the invention and can be used as fungicides.

The novel compounds of the general formula I can be prepared, for example, by the following processes. ##STR6##

The β-ketoesters of the general formula II may be converted into the novel compounds of the general formula I by reacting them with O-methylhydroxylamine (cf. e.g. H. V. Secor and E. B. Sanders, J. Org. Chem. 43 (1978), 2539-2541) or by reacting them first with hydroxylamine to give the corresponding oxime and then reacting the latter with a methylating agent, e.g. methyl iodide or dimethyl sulfate (cf. also European Patent 253,213).

The β-ketoesters of the general structure II are novel and useful intermediates and likewise form the subject of this invention. ##STR7## They can be prepared by conventional processes (cf. F. W. Swamer and Ch. R. Hauser, J. Am. Chem. Soc. 72 (1950), 1352-1356), by reacting an acetophenone of the general formula III, in a suitable solvent, e.g. diethyl ether, with dimethyl carbonate in the presence of a suitable base, e.g. sodium hydride or sodium methoxide.

Acetophenone derivatives of the general formula IIIa (X═CH₂ O) can be prepared in a conventional manner by reacting a benzyl halide of the general formula IV, where Hal is halogen and R_(m) has the abovementioned meanings, with 2-hydroxyacetophenone in the presence of a base, e.g. sodium carbonate, and of a suitable solvent, e.g. methanol. ##STR8##

Acetophenone derivatives of the general formula IIIb (X═OCH₂) can be prepared in a conventional manner by reacting a phenol of the general formula V, where R_(m) has the abovementioned meanings, with 2-cyanobenzyl bromide in the presence of a base, e.g. sodium carbonate, and of a suitable solvent, e.g. methanol. ##STR9## The resulting nitrile of the general formula VI can be converted into the acetophenone IIIb by a Grignard reaction with a methylmagnesium halide (cf. E. C. Ashby et al., J. Am. Chem. Soc. 95 (1973), 4896, 5186).

If the analogous thiophenols of the general formula VII are used as starting materials, the acetophenone derivatives of the general formula IIIc (X═SCH₂) are obtained by the same route ##STR10##

Acetophenone derivatives of the general formula IIId (X═CH═CH) can be prepared in a known manner by subjecting 2-cyanobenzaldehyde to a Wittig reaction (cf. G. Wittig and U. Schollkopf, Org. Synth. Coll. Vol. V, 751 (1973)) with a benzylphosphonium halide of the general formula VIII, where R_(m) has the abovementioned meanings. ##STR11## The resulting nitrile of the general formula IX can be converted into the acetophenone IIId by a Grignard reaction with a methylmagnesium halide (cf. E. C. Ashby et al., J. Am. Chem. Soc. 95 (1973), 4896, 5186).

By reducing the double bond either catalytically with hydrogen (cf. Houben-Weyl, Methoden der organischen Chemie V/2b, 264-267 (1981)) or with diimine (cf. E. E. van Tamelen et al., J. Am. Chem. Soc. 83 (1961), 4302), the acetophenone derivatives of the general formula IIIe (X═CH₂ --CH₂) can be prepared therefrom.

Acetophenone derivatives of the general formula IIIf (X═O) can be prepared, for example, in a known manner (T. W. Harris et al., J. Med. Chem. 25 (1982), 855-858), by reacting 2-chloroacetophenone with a phenol of the formula V in the presence of copper powder and potassium carbonate. ##STR12##

The Examples which follow illustrate the preparation of the novel compounds according to the invention:

METHOD 1 2-(2-Methylbenzyloxy)-acetophenone

102 g (0.75 mol) of 2-hydroxyacetophenone and 102 g (0.75 mol) of potassium carbonate in 500 ml of absolute ethanol are initially taken. 139 g (0.75 mol) of 2-methylbenzyl bromide are added dropwise and the mixture is refluxed for 10 h. The mixture is cooled and filtered under suction, after which the filtrate is evaporated down. The crude product is recrystallized from diethyl ether. 106 g (59%) of product are obtained as crystals (mp.=53°-55° C.).

METHOD 2 Methyl 3-[2-(2-methylbenzyloxy)-phenyl]-3-oxopropionate

14 g (0.6 mol) of 100% pure sodium hydride and 54 g (0.6 mol) of dimethyl carbonate in 225 ml of absolute diethyl ether are initially taken under nitrogen. 72 g (0.3 mol) of 2-(2-methylbenzyloxy)-acetophenone, dissolved in 300 ml of absolute ether, are added dropwise at 20°-35° C. and the mixture is refluxed for 5 h. At 10° C., first 45 ml of methanol and then 100 ml of H₂ O are slowly added dropwise. The pH is then brought to 7 with dilute hydrochloric acid. The organic phase is washed several times with H₂ O, dried over sodium sulfate and evaporated down. The product is obtained in quantitative yield as crystals (mp.=38°-42° C.).

¹ H-NMR: δ=2.39 (s, 3H); 3.55 (s, 2H); 5.15 (s, 2H), 7.0-7.9 (m, 8H).

PREPARATION EXAMPLE 1 Methyl 3-[2-(2-methylbenzyloxy)-phenyl]-3-methoximinopropionate (compound No. 66)

14.9 g (0.05 mol) of methyl 3-[2-(2-methylbenzyloxy)-phenyl]-3-oxopropionate and 8.35 g (0.1 mol) of O-methylhydroxylamine hydrochloride in 250 ml of pyridine are initially taken and then stirred for 18 h at 70° C. The mixture is then evaporated down under reduced pressure. The residue is taken up in ethyl acetate and the solution is washed thoroughly with H₂ O, dried over sodium sulfate and evaporated down again. 12 g (73%) of the desired ester are obtained as an oil (isomer ratio 85:15).

¹ H-NMR (CDCl₃): δ=2.35 (m, 3H); 3.30/3.59 (2×s, 3H); 3.56/3.75 (2×s, 2H); 3.85/3.96 (2×s, 3H); 5.05 (s, 2H); 6.9-7.5 (m, 8H).

The following compounds can be prepared in a similar manner.

                                      TABLE 1                                      __________________________________________________________________________      ##STR13##                                   (I)                               No.  R.sub.m          X     mp (°C.)                                                                     IR(cm.sup.-1)                                 __________________________________________________________________________     1    H                CH.sub.2 O                                               2    2-F              CH.sub.2 O                                               3    3-F              CH.sub.2 O                                               4    4-F              CH.sub.2 O                                                                           oil  2940,1741,1512,1226,1050,754                  5    2,3-F.sub.2      CH.sub.2 O                                               6    2,4-F.sub.2      CH.sub.2 O                                               7    2,4,6-F.sub.3    CH.sub.2 O                                               8    2,3,4,5,6-F.sub.5                                                                               CH.sub.2 O                                               9    2-Cl             CH.sub.2 O                                               10   3-Cl             CH.sub.2 O                                               11   4-Cl             CH.sub.2 O                                                                           oil  2940,1741,1494,1234,1050,754                  12   2,3-Cl.sub.2     CH.sub.2 O                                               13   2,4-Cl.sub.2     CH.sub.2 O                                               14   2,5-Cl.sub.2     CH.sub.2 O                                               15   2,6-Cl.sub.2     CH.sub.2 O                                               16   3,4-Cl.sub.2     CH.sub.2 O                                               17   3,5-Cl.sub.2     CH.sub.2 O                                               18   2,3,4-Cl.sub.3   CH.sub.2 O                                               19   2,3,5-Cl.sub.3   CH.sub.2 O                                               20   2,3,6-Cl.sub.3   CH.sub.2 O                                               21   2,4,5-Cl.sub.3   CH.sub.2 O                                               22   2,4,6-Cl.sub.3   CH.sub.2 O                                               23   3,4,5-Cl.sub.3   CH.sub.2 O                                               24   2,3,4,6-Cl.sub. 4                                                                               CH.sub.2 O                                               25   2,3,5,6-Cl.sub.4 CH.sub.2 O                                               26   2,3,4,5,6-Cl.sub.5                                                                              CH.sub.2 O                                               27   2-Br             CH.sub.2 O                                               28   3-Br             CH.sub.2 O                                               29   4-Br             CH.sub.2 O                                                                           91-95                                                                               2940,1746,1447,1176,1044,751                  30   2,4-Br.sub.2     CH.sub.2 O                                               31   2,5-Br.sub.2     CH.sub.2 O                                               32   2,6-Br.sub.2     CH.sub.2 O                                               33   2,4,6-Br.sub.3   CH.sub.2 O                                               34   2,3,4,5,6-Br.sub.5                                                                              CH.sub.2 O                                               35   2-I              CH.sub.2 O                                               36   2-I              CH.sub.2 O                                               37   4-I              CH.sub.2 O                                               38   2,4-I.sub.2      CH.sub.2 O                                               39   2-Cl, 4-F        CH.sub.2 O                                               40   2-Cl, 4-F        CH.sub.2 O                                               41   2-Cl, 5-F        CH.sub.2 O                                               42   2-Cl, 6-F        CH.sub.2 O                                               43   2-Cl, 3-Br       CH.sub.2 O                                               44   2-Cl, 4-Br       CH.sub.2 O                                               45   2-Cl, 5-Br       CH.sub.2 O                                               46   2-Cl, 6-Br       CH.sub.2 O                                               47   2-Br, 3-Cl       CH.sub.2 O                                               48   2-Br, 4-Cl       CH.sub.2 O                                               49   2-Br, 5-Cl       CH.sub.2 O                                               50   2-Br, 3-F        CH.sub.2 O                                               51   2-Br, 4-F        CH.sub.2 O                                               52   2-Br, 5-F        CH.sub.2 O                                               53   2-Br, 6-F        CH.sub.2 O                                               54   2-F, 3-Cl        CH.sub.2 O                                               55   2-F, 4-Cl        CH.sub.2 O                                               56   2-F, 5-Cl        CH.sub.2 O                                               57   3-Cl, 4-F        CH.sub.2 O                                               58   3-Cl, 5-F        CH.sub.2 O                                               59   3-Cl, 4-Br       CH.sub.2 O                                               60   3-Cl, 5-Br       CH.sub.2 O                                               61   3-F, 4-Cl        CH.sub.2 O                                               62   3-F, 4-Br        CH.sub.2 O                                               63   3-Br, 4-Cl       CH.sub.2 O                                               64   3-Br, 4-F        CH.sub.2 O                                               65   2,6-Cl.sub.2, 4-Br                                                                              CH.sub.2 O                                               66   2-CH.sub.3       CH.sub.2 O                                                                           oil  2940,1742,1450,1231,1050,751                  67   3-CH.sub.3       CH.sub.2 O                                               68   4-CH.sub.3       CH.sub.2 O                                               69   2,3-(CH.sub.3).sub.2                                                                            CH.sub.2 O                                               70   2,4-(CH.sub.3).sub.2                                                                            CH.sub.2 O                                               71   2,5-(CH.sub.3).sub.2                                                                            CH.sub.2 O                                               72   2,6-(CH.sub.3).sub.2                                                                            CH.sub.2 O                                               73   3,4-(CH.sub.3).sub.2                                                                            CH.sub.2 O                                               74   3,5-(CH.sub.3).sub.2                                                                            CH.sub.2 O                                               75   2,3,4-(CH.sub.3).sub.3                                                                          CH.sub.2 O                                               76   2,3,5-(CH.sub.3).sub.3                                                                          CH.sub.2 O                                               77   2,3,6-(CH.sub.3).sub.3                                                                          CH.sub.2 O                                               78   2,4,5-(CH.sub.3).sub.3                                                                          CH.sub.2 O                                               79   2,4,6-(CH.sub.3).sub.3                                                                          CH.sub.2 O                                               80   3,4,5-(CH.sub.3).sub.3                                                                          CH.sub.2 O                                               81   2,3,4,6-(CH.sub.3).sub.4                                                                        CH.sub.2 O                                               82   2,3,5,6-(CH.sub.3).sub.4                                                                        CH.sub.2 O                                               83   2,3,4,5,6-(CH.sub.3).sub.5                                                                      CH.sub.2 O                                               84   2-C.sub.2 H.sub.5                                                                               CH.sub.2 O                                               85   3-C.sub.2 H.sub.5                                                                               CH.sub.2 O                                               86   4-C.sub.2 H.sub.5                                                                               CH.sub.2 O                                               87   2,4-(C.sub.2 H.sub.5).sub.2                                                                     CH.sub.2 O                                               88   2,6-(C.sub.2 H.sub.5).sub.2                                                                     CH.sub.2 O                                               89   3,5-(C.sub.2 H.sub.5).sub.2                                                                     CH.sub.2 O                                               90   2,4,6-(C.sub.2 H.sub.5).sub.3                                                                   CH.sub.2 O                                               91   2-n-C.sub.3 H.sub.7                                                                             CH.sub.2 O                                               92   3-n-C.sub.3 H.sub.7                                                                             CH.sub.2 O                                               93   4-n-C.sub.3 H.sub.7                                                                             CH.sub.2 O                                               94   2-i-C.sub.2 H.sub.7                                                                             CH.sub.2 O                                               95   3-i-C.sub.2 H.sub.7                                                                             CH.sub.2 O                                               96   4-i-C.sub.3 H.sub.7                                                                             CH.sub.2 O                                               97   2,4-(i-C.sub.3 H.sub.7).sub.2                                                                   CH.sub.2 O                                               98   2,6-(i-C.sub.3 H.sub.7).sub.2                                                                   CH.sub.2 O                                               99   3,5-(i-C.sub.3 H.sub.7).sub.2                                                                   CH.sub.2 O                                               100  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 CH.sub.2 O                                               101  2-s-C.sub.4 H.sub.9                                                                             CH.sub.2 O                                               102  3-s-C.sub.4 H.sub.9                                                                             CH.sub.2 O                                               103  4-s-C.sub.4 H.sub.9                                                                             CH.sub.2 O                                               104  2-t-C.sub.4 H.sub.9                                                                             CH.sub.2 O                                               105  3-t-C.sub.4 H.sub.9                                                                             CH.sub.2 O                                               106  4-t-C.sub.4 H.sub.9                                                                             CH.sub.2 O                                               107  2,3-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2 O                                               108  2,4-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2 O                                               109  2,5-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2 O                                               110  2,6-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2 O                                               111  3,5-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2 O                                               112  2,4,6-(t-C.sub.4 H.sub.9).sub.3                                                                 CH.sub.2 O                                               113  4-n-C.sub.9 H.sub.19                                                                            CH.sub.2 O                                               114  4-n-C.sub.12 H.sub.25                                                                           CH.sub.2 O                                               115  3-n-C.sub.15 H.sub.31                                                                           CH.sub.2 O                                               116  4-(1,1,3,3,-tetramethylbutyl)                                                                   CH.sub.2 O                                               117  4-(1,1,3,-trimethylbutyl)                                                                       CH.sub.2 O                                               118  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                                                 CH.sub.2 O                                               119  2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                                                 CH.sub.2 O                                               120  2,6-(t-C.sub.4 H.sub.9).sub.2, 4-CH.sub.3                                                       CH.sub.2 O                                               121  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                                                 CH.sub.2 O                                               122  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                                                 CH.sub.2 O                                               123  2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 CH.sub.2 O                                               124  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                                                 CH.sub.2 O                                               125  3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 CH.sub.2 O                                               126  2-i-C.sub.3 H.sub.7, 5-CH.sub.3                                                                 CH.sub.2 O                                               127  2,4-(t-C.sub.4 H.sub.9).sub.2, 6-i-C.sub.3 H.sub.7                                              CH.sub.2 O                                               128  2-C.sub.3 H.sub.5 (= allyl)                                                                     CH.sub.2 O                                               129  3-C.sub.3 H.sub.5                                                                               CH.sub.2 O                                               130  4-C.sub.3 H.sub.5                                                                               CH.sub.2 O                                               131  2-C.sub.3 H.sub.5, 6-CH.sub.3                                                                   CH.sub.2 O                                               132  2-cyclo-C.sub.6 H.sub.11                                                                        CH.sub.2 O                                               133  3-cyclo-C.sub.6 H.sub.11                                                                        CH.sub.2 O                                               134  4-cyclo-C.sub.6 H.sub.11                                                                        CH.sub.2 O                                               135  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                                                  CH.sub.2 O                                               136  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                                            CH.sub.2 O                                               137  2-CH.sub.3, 4-(1,1,3,3-tetramethylbutyl)                                                        CH.sub.2 O                                               138  2-CH.sub.2 C.sub.6 H.sub.5                                                                      CH.sub.2 O                                               139  3-CH.sub.2 C.sub.6 H.sub.5                                                                      CH.sub.2 O                                               140  4-CH.sub.2 C.sub.6 H.sub.5                                                                      CH.sub.2 O                                               141  2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                                          CH.sub.2 O                                               142  2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                                          CH.sub.2 O                                               143  2-C.sub.6 H.sub.5                                                                               CH.sub.2 O                                               144  3-C.sub.6 H.sub.5                                                                               CH.sub.2 O                                               145  4-C.sub.6 H.sub.5                                                                               CH.sub.2 O                                               146  4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                                          CH.sub.2 O                                               147  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                                         CH.sub.2 O                                               148  2-Cl, 4-C.sub.6 H.sub.5                                                                         CH.sub.2 O                                               149  2-Br, 4-C.sub.6 H.sub.5                                                                         CH.sub.2 O                                               150  2-C.sub.6 H.sub.5, 4-Cl                                                                         CH.sub.2 O                                               151  2-C.sub.6 H.sub.5, 4-Br                                                                         CH.sub.2 O                                               152  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                                                CH.sub.2 O                                               153  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                                                CH.sub.2 O                                               154  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                                                CH.sub.2 O                                               155  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                                                CH.sub.2 O                                               156  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                                                  CH.sub.2 O                                               157  2-cyclo-C.sub.6 H.sub.11, 4-Br                                                                  CH.sub.2 O                                               158  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                                                  CH.sub.2 O                                               159  2-Br, 4-cyclo-C.sub.6 H.sub.11                                                                  CH.sub.2 O                                               160  2-OCH.sub.3      CH.sub.2 O                                               161  3-OCH.sub.3      CH.sub.2 O                                               162  4-OCH.sub.3      CH.sub.2 O                                               163  2,4-(OCH.sub.3).sub.2                                                                           CH.sub.2 O                                               164  2-OC.sub.2 H.sub.5                                                                              CH.sub.2 O                                               165  3-OC.sub.2 H.sub.5                                                                              CH.sub.2 O                                               166  4-OC.sub.2 H.sub.5                                                                              CH.sub.2 O                                               167  2-OCH.sub.2 C.sub.6 H.sub.5                                                                     CH.sub.2 O                                               168  3-OCH.sub.2 C.sub.6 H.sub.5                                                                     CH.sub.2 O                                               169  4-OCH.sub.2 C.sub.6 H.sub.5                                                                     CH.sub. 2 O                                              170  2-O-t-C.sub.4 H.sub.9                                                                           CH.sub.2 O                                               171  3-O-t-C.sub.4 H.sub.9                                                                           CH.sub.2 O                                               172  4-O-t-C.sub.4 H.sub.9                                                                           CH.sub.2 O                                               173  2-OC.sub.6 H.sub.5                                                                              CH.sub.2 O                                               174  3-OC.sub.6 H.sub.5                                                                              CH.sub.2 O                                               175  4-OC.sub.6 H.sub.5                                                                              CH.sub.2 O                                               176  2-CF.sub.3       CH.sub.2 O                                               177  3-CF.sub.3       CH.sub.2 O                                               178  4-CF.sub.3       CH.sub.2 O                                               179  2-OCF.sub.3      CH.sub.2 O                                               180  3-OCF.sub.3      CH.sub.2 O                                               181  4-OCF.sub.3      CH.sub.2 O                                               182  3-OCH.sub.2 CHF.sub.2                                                                           CH.sub.2 O                                               183  3-OCF.sub.2 CHF.sub.2                                                                           CH.sub.2 O                                               184  3-OC.sub.2 H.sub.5                                                                              CH.sub.2 O                                               185  2-NO.sub.2       CH.sub.2 O                                               186  3-NO.sub.2       CH.sub.2 O                                               187  4-NO.sub.2       CH.sub.2 O                                               188  2-CN             CH.sub.2 O                                               189  3-CN             CH.sub.2 O                                               190  4-CN             CH.sub.2 O                                               191  2-CH.sub.3, 3-Cl CH.sub.2 O                                               192  2-CH.sub.3, 4-Cl CH.sub.2 O                                               193  2-CH.sub.3, 5-Cl CH.sub.2 O                                               194  2-CH.sub.3, 6-Cl CH.sub.2 O                                               195  2-CH.sub.3, 3-F  CH.sub.2 O                                               196  2-CH.sub.3, 4-F  CH.sub.2 O                                               197  2-CH.sub.3, 5-F  CH.sub.2 O                                               198  2-CH.sub.3, 6-F  CH.sub.2 O                                               199  2-CH.sub.3, 3-Br CH.sub.2 O                                               200  2-CH.sub.3, 4-Br CH.sub.2 O                                               201  2-CH.sub.3, 5-Br CH.sub.2 O                                               202  2-CH.sub.3, 6-Br CH.sub.2 O                                               203  2-Cl, 3-CH.sub.3 CH.sub.2 O                                               204  2-Cl, 4-CH.sub.3 CH.sub.2 O                                               205  2-Cl, 5-CH.sub.3 CH.sub.2 O                                               206  2-F, 3-CH.sub.3  CH.sub.2 O                                               207  2-F, 4-CH.sub.3  CH.sub.2 O                                               208  2-F, 5-CH.sub.3  CH.sub.2 O                                               209  2-Br, 3-CH.sub.3 CH.sub.2 O                                               210  2-Br, 4-CH.sub.3 CH.sub.2 O                                               211  2-Br, 5-CH.sub.3 CH.sub.2 O                                               212  3-CH.sub.3, 4-Cl CH.sub.2 O                                               213  3-CH.sub.3, 5-Cl CH.sub.2 O                                               214  3-CH.sub.3, 4-F  CH.sub.2 O                                               215  3-CH.sub.3, 5-F  CH.sub.2 O                                               216  3-CH.sub.3, 4-Br CH.sub.2 O                                               217  3-CH.sub.3, 5-Br CH.sub.2 O                                               218  3-F, 4-CH.sub.3  CH.sub.2 O                                               219  3-Cl, 4-CH.sub.3 CH.sub.2 O                                               220  3-Br, 4-CH.sub.3 CH.sub.2 O                                               221  2-Cl, 4,5-(CH.sub.3).sub.2                                                                      CH.sub.2 O                                               222  2-Br, 4,5-(CH.sub.3).sub.2                                                                      CH.sub.2 O                                               223  2-Cl, 3,5-(CH.sub.3).sub.2                                                                      CH.sub.2 O                                               224  2-Br, 3,5-(CH.sub.3).sub.2                                                                      CH.sub.2 O                                               225  2,6-Cl.sub.2, 4-CH.sub.3                                                                        CH.sub.2 O                                               226  2,6-F.sub.2, 4-CH.sub.3                                                                         CH.sub.2 O                                               227  2,6-Br.sub.2, 4-CH.sub.3                                                                        CH.sub.2 O                                               228  2,4-Cl.sub.2, 6-CH.sub.3                                                                        CH.sub.2 O                                               229  2,4-F.sub.2, 6-CH.sub.3                                                                         CH.sub.2 O                                               230  2,4-Br.sub.2, 6-CH.sub.3                                                                        CH.sub.2 O                                               231  2,6-(CH.sub.3).sub.2, 4-F                                                                       CH.sub.2 O                                               232  2,6-(CH.sub.3).sub.2, 4-Cl                                                                      CH.sub.2 O                                               233  2,6-(CH.sub.3).sub.2, 4-Br                                                                      CH.sub.2 O                                               234  3,5-(CH.sub.3).sub.2, 4-F                                                                       CH.sub.2 O                                               235  3,5-(CH.sub.3).sub.2, 4-Cl                                                                      CH.sub.2 O                                               236  3,5-(CH.sub.3).sub.2, 4-Br                                                                      CH.sub.2 O                                               237  2,3,6-(CH.sub.3).sub.3, 4-F                                                                     CH.sub.2 O                                               238  2,3,6-(CH.sub.3).sub.3, 4-Cl                                                                    CH.sub.2 O                                               239  2,3,6-(CH.sub.3).sub.3, 4-Br                                                                    CH.sub.2 O                                               240  2,4-(CH.sub.3).sub.2, 6-F                                                                       CH.sub.2 O                                               241  2,4-(CH.sub.3).sub.2, 6-Cl                                                                      CH.sub.2 O                                               242  2,4-(CH.sub.3).sub.2, 6-Br                                                                      CH.sub.2 O                                               243  2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                                           CH.sub.2 O                                               244  2-CH.sub.3, 4-Cl, 5-i-C.sub.3 H.sub. 7                                                          CH.sub.2 O                                               245  2-Cl, 3-i-C.sub.3 H.sub.7                                                                       CH.sub.2 O                                               246  2-Cl, 4-i-C.sub.3 H.sub.7                                                                       CH.sub.2 O                                               247  2-Cl, 4-NO.sub.2 CH.sub.2 O                                               248  2-NO.sub.2, 4-Cl CH.sub.2 O                                               249  2-OCH.sub.3, 5-NO.sub.2                                                                         CH.sub.2 O                                               250  2,4-Cl.sub.2, 5-NO.sub.2                                                                        CH.sub.2 O                                               251  2,4-Cl.sub.2, 6-NO.sub.2                                                                        CH.sub.2 O                                               252  2,6-Cl.sub.2, 4-NO.sub.2                                                                        CH.sub.2 O                                               253  2,6-Br.sub.2, 4-NO.sub.2                                                                        CH.sub.2 O                                               254  2,6-I.sub.2, 4-NO.sub.2                                                                         CH.sub.2 O                                               255  H                OCH.sub.2                                                256  2-F              OCH.sub.2                                                257  3-F              OCH.sub.2                                                258  4-F              OCH.sub.2                                                259  2,3-F.sub.2      OCH.sub.2                                                260  2,4-F.sub.2      OCH.sub.2                                                261  2,4,6-F.sub.3    OCH.sub.2                                                262  2,3,4,5,6-F.sub.5                                                                               OCH.sub.2                                                263  2-Cl             OCH.sub.2                                                264  3-Cl             OCH.sub.2                                                265  4-Cl             OCH.sub.2                                                266  2,3-Cl.sub.2     OCH.sub.2                                                267  2,4-Cl.sub.2     OCH.sub.2                                                268  2,5-Cl.sub.2     OCH.sub.2                                                269  2,6-Cl.sub.2     OCH.sub.2                                                270  3,4-Cl.sub.2     OCH.sub.2                                                271  3,5-Cl.sub.2     OCH.sub.2                                                272  2,3,4-Cl.sub.3   OCH.sub.2                                                273  2,3,5-Cl.sub.3   OCH.sub.2                                                274  2,3,6-Cl.sub.3   OCH.sub.2                                                275  2,4,5-Cl.sub.3   OCH.sub.2                                                276  2,4,6-Cl.sub.3   OCH.sub.2                                                277  3,4,5-Cl.sub.3   OCH.sub.2                                                278  2,3,4,6-Cl.sub.4 OCH.sub.2                                                279  2,3,5,6-Cl.sub.4 OCH.sub.2                                                280  2,3,4,5,6-Cl.sub.5                                                                              OCH.sub.2                                                281  2-Br             OCH.sub.2                                                282  3-Br             OCH.sub.2                                                283  4-Br             OCH.sub.2                                                284  2,4-Br.sub.2     OCH.sub.2                                                285  2,5-Br.sub.2     OCH.sub.2                                                286  2,6-Br.sub.2     OCH.sub.2                                                287  2,4,6-Br.sub.3   OCH.sub.2                                                288  2,3,4,5,6-Br.sub.5                                                                              OCH.sub.2                                                289  2-I              OCH.sub.2                                                290  3-I              OCH.sub.2                                                291  4-I              OCH.sub.2                                                292  2,4-I.sub.2      OCH.sub.2                                                293  2-Cl, 3-F        OCH.sub.2                                                294  2-Cl, 4-F        OCH.sub.2                                                295  2-Cl, 5-F        OCH.sub.2                                                296  2-Cl, 3-F        OCH.sub.2                                                297  2-Cl, 3-Br       OCH.sub.2                                                298  2-Cl, 4-Br       OCH.sub.2                                                299  2-Cl, 5-Br       OCH.sub.2                                                300  2-Cl, 6-Br       OCH.sub.2                                                301  2-Br, 3-Cl       OCH.sub.2                                                302  2-Br, 4-Cl       OCH.sub.2                                                303  2-Br, 5-Cl       OCH.sub.2                                                304  2-Br, 3-F        OCH.sub.2                                                305  2-Br, 4-F        OCH.sub.2                                                305  2-Br, 5-F        OCH.sub.2                                                307  2-Br, 6-F        OCH.sub.2                                                308  2-F, 3-Cl        OCH.sub.2                                                309  2-F, 4-Cl        OCH.sub.2                                                310  2-F, 5-Cl        OCH.sub.2                                                311  3-Cl, 4-F        OCH.sub.2                                                312  3-Cl, 5-F        OCH.sub.2                                                313  3-Cl, 4-Br       OCH.sub.2                                                314  3-Cl, 5-Br       OCH.sub.2                                                315  3-F, 4-Cl        OCH.sub.2                                                316  3-F, 4-Br        OCH.sub.2                                                317  3-Br, 4-Cl       OCH.sub.2                                                318  3-Br, 4-F        OCH.sub.2                                                319  2,6-Cl.sub. 2    OCH.sub.2                                                320  2-CH.sub.3       OCH.sub.2                                                321  3-CH.sub.3       OCH.sub.2                                                322  4-CH.sub.3       OCH.sub.2                                                323  2,3-(CH.sub.3).sub.2                                                                            OCH.sub.2                                                324  2,4-(CH.sub.3).sub.2                                                                            OCH.sub.2                                                325  2,5-(CH.sub.3).sub.2                                                                            OCH.sub.2                                                326  2,6-(CH.sub.3).sub.2                                                                            OCH.sub.2                                                327  3,4-(CH.sub.3).sub.2                                                                            OCH.sub.2                                                328  3,5-(CH.sub.3).sub.2                                                                            OCH.sub.2                                                329  2,3,4-(CH.sub.3).sub.3                                                                          OCH.sub.2                                                330  2,3,5-(CH.sub.3).sub.3                                                                          OCH.sub.2                                                331  2,3,6-(CH.sub.3).sub.3                                                                          OCH.sub.2                                                332  2,4,5-(CH.sub.3).sub.3                                                                          OCH.sub.2                                                333  2,4,6-(CH.sub.3).sub.3                                                                          OCH.sub.2                                                334  3,4,5-(CH.sub.3).sub.3                                                                          OCH.sub.2                                                335  2,3,4,6-(CH.sub.3).sub.4                                                                        OCH.sub.2                                                336  2,3,5,6-(CH.sub.3).sub.4                                                                        OCH.sub.2                                                337  2,3,4,5,6,-(CH.sub.3).sub.5                                                                     OCH.sub.2                                                338  2-C.sub.2 H.sub.5                                                                               OCH.sub.2                                                339  3-C.sub.2 H.sub.5                                                                               OCH.sub.2                                                340  4-C.sub.2 H.sub.5                                                                               OCH.sub.2                                                341  2,4-(C.sub.2 H.sub.5).sub.2                                                                     OCH.sub.2                                                342  2,6-(C.sub.2 H.sub.5).sub.2                                                                     OCH.sub.2                                                343  3,5-(C.sub.2 H.sub.5).sub.2                                                                     OCH.sub.2                                                344  2,4,6-(C.sub.2 H.sub.5).sub.3                                                                   OCH.sub.2                                                345  2-n-C.sub.3 H.sub.7                                                                             OCH.sub.2                                                346  3-n-C.sub.3 H.sub.7                                                                             OCH.sub.2                                                347  4-n-C.sub.3 H.sub.7                                                                             OCH.sub. 2                                               348  2-i-C.sub.2 H.sub.7                                                                             OCH.sub.2                                                349  3-i-C.sub.2 H.sub.7                                                                             OCH.sub.2                                                350  4-i-C.sub.3 H.sub.7                                                                             OCH.sub.2                                                351  2,4-(i-C.sub.3 H.sub.7).sub.2                                                                   OCH.sub.2                                                352  2,6-(i-C.sub.3 H.sub.7).sub.2                                                                   OCH.sub.2                                                353  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 OCH.sub.2                                                354  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 OCH.sub.2                                                355  2-s-C.sub.4 H.sub.9                                                                             OCH.sub.2                                                356  3-s-C.sub.4 H.sub.9                                                                             OCH.sub.2                                                357  4-s-C.sub.4 H.sub.9                                                                             OCH.sub.2                                                358  2-t-C.sub.4 H.sub.9                                                                             OCH.sub.2                                                359  3-t-C.sub.4 H.sub.9                                                                             OCH.sub.2                                                360  4-t-C.sub.4 H.sub.9                                                                             OCH.sub.2                                                361  2,3-(t-C.sub.4 H.sub.9).sub.2                                                                   OCH.sub.2                                                362  2,4-(t-C.sub.4 H.sub.9).sub.2                                                                   OCH.sub.2                                                363  2,5-(t-C.sub.4 H.sub.9).sub.2                                                                   OCH.sub.2                                                364  2,6-(t-C.sub.4 H.sub.9).sub.2                                                                   OCH.sub.2                                                365  3,5-(t-C.sub.4 H.sub.9).sub.2                                                                   OCH.sub.2                                                366  2,4,6-(t-C.sub.4 H.sub.9).sub.3                                                                 OCH.sub.2                                                367  4-n-C.sub.9 H.sub.19                                                                            OCH.sub.2                                                368  4-n-C.sub.12 H.sub.25                                                                           OCH.sub.2                                                369  3-n-C.sub.15 H.sub.31                                                                           OCH.sub.2                                                370  4-(1,1,3,3,-tetramethylbutyl)                                                                   OCH.sub.2                                                371  4-(1,1,3,-trimethylbutyl)                                                                       OCH.sub.2                                                372  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                                                 OCH.sub.2                                                373  2-t-C.sub.4 H.sub.9, 5-CH.sub. 3                                                                OCH.sub.2                                                374  2,6-(t-C.sub.4 H.sub.9).sub.2, 4-CH.sub.3                                                       OCH.sub.2                                                375  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                                                 OCH.sub.2                                                376  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                                                 OCH.sub.2                                                377  2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 OCH.sub.2                                                378  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                                                 OCH.sub.2                                                379  3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 OCH.sub.2                                                380  2-i-C.sub.3 H.sub.7, 5-CH.sub.3                                                                 OCH.sub.2                                                381  2,4-(t-C.sub.4 H.sub.9).sub.2, 6-i-C.sub.3 H.sub.7                                              OCH.sub.2                                                382  2-C.sub.3 H.sub.5 (= allyl)                                                                     OCH.sub.2                                                383  3-C.sub.3 H.sub.5                                                                               OCH.sub.2                                                384  4-C.sub.3 H.sub.5                                                                               OCH.sub.2                                                385  2-C.sub.3 H.sub.5, 6-CH.sub.3                                                                   OCH.sub.2                                                386  2-cyclo-C.sub.6 H.sub.11                                                                        OCH.sub.2                                                387  3-cyclo-C.sub.6 H.sub.11                                                                        OCH.sub.2                                                388  4-cyclo-C.sub.6 H.sub.11                                                                        OCH.sub.2                                                389  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                                                  OCH.sub.2                                                390  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                                            OCH.sub.2                                                391  2-CH.sub.3, 4-(1,1,3,3-tetramethylbutyl)                                                        OCH.sub.2                                                392  2-CH.sub.2 C.sub.6 H.sub.5                                                                      OCH.sub.2                                                393  3-CH.sub.2 C.sub.6 H.sub.5                                                                      OCH.sub.2                                                394  4-CH.sub.2 C.sub.6 H.sub.5                                                                      OCH.sub. 2                                               395  2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                                          OCH.sub.2                                                396  2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                                          OCH.sub.2                                                397  2-C.sub.6 H.sub.5                                                                               OCH.sub.2                                                398  3-C.sub.6 H.sub.5                                                                               OCH.sub.2                                                399  4-C.sub.6 H.sub.5                                                                               OCH.sub.2                                                400  4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                                          OCH.sub.2                                                401  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                                         OCH.sub.2                                                402  2-Cl, 4-C.sub.6 H.sub.5                                                                         OCH.sub.2                                                403  2-Br, 4-C.sub.6 H.sub.5                                                                         OCH.sub.2                                                404  2-C.sub.6 H.sub.5, 4-Cl                                                                         OCH.sub.2                                                405  2-C.sub.6 H.sub.5, 4-Br                                                                         OCH.sub.2                                                406  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                                                OCH.sub.2                                                407  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                                                OCH.sub.2                                                408  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                                                OCH.sub.2                                                409  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                                                OCH.sub.2                                                410  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                                                  OCH.sub.2                                                411  2-cyclo-C.sub.6 H.sub.11, 4-Br                                                                  OCH.sub.2                                                412  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                                                  OCH.sub.2                                                413  2-Br, 4-cyclo-C.sub.6 H.sub.11                                                                  OCH.sub.2                                                414  2-OCH.sub.3      OCH.sub.2                                                415  3-OCH.sub.3      OCH.sub.2                                                416  4-OCH.sub.3      OCH.sub.2                                                417  2,4-(OCH.sub.3).sub.2                                                                           OCH.sub.2                                                418  2-OC.sub.2 H.sub.5                                                                              OCH.sub.2                                                419  3-OC.sub.2 H.sub.5                                                                              OCH.sub.2                                                420  4-OC.sub.2 H.sub.5                                                                              OCH.sub.2                                                421  2-OCH.sub.2 C.sub.6 H.sub.5                                                                     OCH.sub.2                                                422  3-OCH.sub.2 C.sub.6 H.sub.5                                                                     OCH.sub.2                                                423  4-OCH.sub.2 C.sub.6 H.sub.5                                                                     OCH.sub.2                                                424  2-O-t-C.sub.4 H.sub.9                                                                           OCH.sub.2                                                425  3-O-t-C.sub.4 H.sub.9                                                                           OCH.sub.2                                                426  4-O-t-C.sub.4 H.sub.9                                                                           OCH.sub.2                                                427  2-OC.sub.6 H.sub.5                                                                              OCH.sub.2                                                428  3-OC.sub.6 H.sub.5                                                                              OCH.sub.2                                                429  4-OC.sub.6 H.sub.5                                                                              OCH.sub.2                                                430  2-CF.sub.3       OCH.sub.2                                                431  3-CF.sub.3       OCH.sub.2                                                432  4-CF.sub.3       OCH.sub.2                                                433  2-OCF.sub.3      OCH.sub.2                                                434  3-OCF.sub.3      OCH.sub.2                                                435  4-OCF.sub.3      OCH.sub.2                                                436  3-OCH.sub.2 CHF.sub.2                                                                           OCH.sub.2                                                437  3-OCF.sub.2 CHF.sub.2                                                                           OCH.sub.2                                                438  3-OC.sub.2 H.sub.5                                                                              OCH.sub.2                                                439  2-NO.sub.2       OCH.sub.2                                                440  3-NO.sub.2       OCH.sub.2                                                441  4-NO.sub.2       OCH.sub.2                                                442  2-CN             OCH.sub.2                                                443  3-CN             OCH.sub.2                                                444  4-CN             OCH.sub.2                                                445  2-CH.sub.3, 3-Cl OCH.sub.2                                                446  2-CH.sub.3, 4-Cl OCH.sub.2                                                447  2-CH.sub.3, 5-Cl OCH.sub.2                                                448  2-CH.sub.3, 6-Cl OCH.sub.2                                                449  2-CH.sub. 3, 3-F OCH.sub.2                                                450  2-CH.sub.3, 4-F  OCH.sub.2                                                451  2-CH.sub.3, 5-F  OCH.sub.2                                                452  2-CH.sub.3, 6-F  OCH.sub.2                                                453  2-CH.sub.3, 3-Br OCH.sub.2                                                454  2-CH.sub.3, 4-Br OCH.sub.2                                                455  2-CH.sub.3, 5-Br OCH.sub.2                                                456  2-CH.sub.3, 6-Br OCH.sub.2                                                457  2-Cl, 3-CH.sub.3 OCH.sub.2                                                458  2-Cl, 4-CH.sub.3 OCH.sub.2                                                459  2-Cl, 5-CH.sub.3 OCH.sub.2                                                460  2-F, 3-CH.sub.3  OCH.sub.2                                                461  2-F, 4-CH.sub.3  OCH.sub.2                                                462  2-F, 5-CH.sub.3  OCH.sub.2                                                463  2-Br, 3-CH.sub.3 OCH.sub.2                                                464  2-Br, 4-CH.sub.3 OCH.sub.2                                                465  2-Br, 5-CH.sub.3 OCH.sub.2                                                466  3-CH.sub.3, 4-Cl OCH.sub.2                                                467  3-CH.sub.3, 5-Cl OCH.sub.2                                                468  3-CH.sub.3, 4-F  OCH.sub.2                                                469  3-CH.sub.3, 5-F  OCH.sub.2                                                470  3-CH.sub.3, 4-Br OCH.sub.2                                                471  3-CH.sub.3, 5-Br OCH.sub.2                                                472  3-F, 4-CH.sub.3  OCH.sub.2                                                473  3-Cl, 4-CH.sub.3 OCH.sub.2                                                474  3-Br, 4-CH.sub.3 OCH.sub.2                                                475  2-Cl, 4,5-(CH.sub.3).sub.2                                                                      OCH.sub.2                                                476  2-Br, 4,5-(CH.sub.3).sub.2                                                                      OCH.sub.2                                                477  2-Cl, 3,5-(CH.sub.3).sub.2                                                                      OCH.sub.2                                                478  2-Br, 3,5-(CH.sub.3).sub.2                                                                      OCH.sub.2                                                479  2,6-Cl.sub.2, 4-CH.sub.3                                                                        OCH.sub.2                                                480  2,6-F.sub.2, 4-CH.sub.3                                                                         OCH.sub.2                                                481  2,6-Br.sub.2, 4-CH.sub.3                                                                        OCH.sub.2                                                482  2,4-Cl.sub.2, 6-CH.sub.3                                                                        OCH.sub.2                                                483  2,4-F.sub.2, 6-CH.sub.3                                                                         OCH.sub.2                                                484  2,4-Br.sub.2, 6-CH.sub.3                                                                        OCH.sub.2                                                485  2,6-(CH.sub.3).sub.2, 4-F                                                                       OCH.sub.2                                                486  2,6-(CH.sub.3).sub.2, 4-Cl                                                                      OCH.sub.2                                                487  2,6-(CH.sub.3).sub.2, 4-Br                                                                      OCH.sub.2                                                488  3,5-(CH.sub.3).sub.2, 4-F                                                                       OCH.sub.2                                                489  3,5-(CH.sub.3).sub.2, 4-Cl                                                                      OCH.sub.2                                                490  3,5-(CH.sub.3).sub.2, 4-Br                                                                      OCH.sub.2                                                491  2,3,6-(CH.sub.3).sub.3, 4-F                                                                     OCH.sub.2                                                492  2,3,6-(CH.sub.3).sub.3, 4-Cl                                                                    OCH.sub.2                                                493  2,3,6-(CH.sub.3).sub.3, 4-Br                                                                    OCH.sub.2                                                494  2,4-(CH.sub.3).sub.2, 6-F                                                                       OCH.sub.2                                                495  2,4-(CH.sub.3).sub.2, 6-Cl                                                                      OCH.sub.2                                                496  2,4-(CH.sub.3).sub.2, 6-Br                                                                      OCH.sub.2                                                497  2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                                           OCH.sub.2                                                498  2-CH.sub.3, 4-Cl, 5-i-C.sub.3 H.sub.7                                                           OCH.sub.2                                                499  2-Cl, 3-i-C.sub.3 H.sub.7                                                                       OCH.sub.2                                                500  2-Cl, 4-i-C.sub.3 H.sub.7                                                                       OCH.sub.2                                                501  2-Cl, 4-NO.sub.2 OCH.sub.2                                                502  2-NO.sub.2, 4-Cl OCH.sub.2                                                503  2-OCH.sub.3, 5-NO.sub.2                                                                         OCH.sub.2                                                504  2,4-Cl.sub.2, 5-NO.sub.2                                                                        OCH.sub.2                                                505  2,4-Cl.sub.2, 6-NO.sub.2                                                                        OCH.sub.2                                                506  2,6-Cl.sub.2, 4-NO.sub.2                                                                        OCH.sub.2                                                507  2,6-Br.sub.2, 4-NO.sub.2                                                                        OCH.sub.2                                                508  2,6-I.sub.2, 4-NO.sub.2                                                                         OCH.sub.2                                                509  H                CH.sub.2CH.sub.2                                         510  2-F              CH.sub.2CH.sub.2                                         511  3-F              CH.sub.2CH.sub.2                                         512  4-F              CH.sub.2CH.sub.2                                         513  2,3-F.sub.2      CH.sub.2CH.sub.2                                         514  2,4-F.sub.2      CH.sub.2CH.sub.2                                         515  2,4,6-F.sub.3    CH.sub.2CH.sub.2                                         516  2,3,4,5,6-F.sub.5                                                                               CH.sub.2CH.sub.2                                         517  2-Cl             CH.sub.2CH.sub.2                                         518  3-Cl             CH.sub.2CH.sub.2                                         519  4-Cl             CH.sub.2CH.sub.2                                         520  2,3-Cl.sub.2     CH.sub.2CH.sub.2                                         521  2,4-Cl.sub.2     CH.sub.2CH.sub.2                                         522  2,5-Cl.sub.2     CH.sub.2CH.sub.2                                         523  2,6-Cl.sub.2     CH.sub.2CH.sub.2                                         524  3,4-Cl.sub.2     CH.sub.2CH.sub.2                                         525  3,5-Cl.sub.2     CH.sub.2CH.sub.2                                         526  2,3,4-Cl.sub.3   CH.sub.2CH.sub.2                                         527  2,3,5-Cl.sub.3   CH.sub.2CH.sub.2                                         528  2,3,6-Cl.sub.3   CH.sub.2CH.sub.2                                         529  2,4,5-Cl.sub.3   CH.sub.2CH.sub.2                                         530  2,4,6-Cl.sub.3   CH.sub.2CH.sub. 2                                        531  3,4,5-Cl.sub.3   CH.sub.2CH.sub.2                                         532  2,3,4,6-Cl.sub.4 CH.sub.2CH.sub.2                                         533  2,3,5,6-Cl.sub.4 CH.sub.2CH.sub.2                                         534  2,3,4,5,6-Cl.sub.5                                                                              CH.sub.2CH.sub.2                                         535  2-Br             CH.sub.2CH.sub.2                                         536  3-Br             CH.sub.2CH.sub.2                                         537  4-Br             CH.sub.2CH.sub.2                                         538  2,4-Br.sub.2     CH.sub.2CH.sub.2                                         539  2,5-Br.sub.2     CH.sub.2CH.sub.2                                         540  2,6-Br.sub.2     CH.sub.2CH.sub.2                                         541  2,4,6-Br.sub.3   CH.sub.2CH.sub.2                                         542  2,3,4,5,6-Br.sub.5                                                                              CH.sub.2CH.sub.2                                         543  2-I              CH.sub.2CH.sub.2                                         544  3-I              CH.sub.2CH.sub.2                                         545  4-I              CH.sub.2CH.sub.2                                         546  2,4-I.sub.2      CH.sub.2CH.sub.2                                         547  2-Cl, 3-F        CH.sub.2CH.sub.2                                         548  2-Cl, 4-F        CH.sub.2CH.sub.2                                         549  2-Cl, 5-F        CH.sub.2CH.sub.2                                         550  2-Cl, 6-F        CH.sub.2CH.sub.2                                         551  2-Cl, 3-Br       CH.sub.2CH.sub.2                                         552  2-Cl, 4-Br       CH.sub.2CH.sub.2                                         553  2-Cl, 5-Br       CH.sub.2CH.sub.2                                         554  2-Cl, 6-Br       CH.sub.2CH.sub.2                                         555  2-Br, 3-Cl       CH.sub.2CH.sub.2                                         556  2-Br, 4-Cl       CH.sub.2CH.sub.2                                         357  2-Br, 5-Cl       CH.sub.2CH.sub.2                                         558  2-Br, 3-F        CH.sub.2CH.sub.2                                         559  2-Br, 4-F        CH.sub.2CH.sub.2                                         560  2-Br, 5-F        CH.sub.2CH.sub.2                                         561  2-Br, 6-F        CH.sub.2CH.sub.2                                         562  2-F, 3-Cl        CH.sub.2CH.sub.2                                         563  2-F, 4-Cl        CH.sub.2CH.sub.2                                         564  2-F, 5-Cl        CH.sub.2CH.sub.2                                         565  3-Cl, 4-F        CH.sub.2CH.sub.2                                         566  3-Cl, 5-F        CH.sub.2CH.sub.2                                         567  3-Cl, 4-Br       CH.sub.2CH.sub.2                                         568  3-Cl, 5-Br       CH.sub.2CH.sub.2                                         569  3-F, 4-Cl        CH.sub.2CH.sub.2                                         570  3-F, 4-Br        CH.sub.2CH.sub.2                                         571  3-Br, 4-Cl       CH.sub.2CH.sub.2                                         572  3-Br, 4-F        CH.sub.2CH.sub.2                                         573  2,6-Cl.sub.2, 4-Br                                                                              CH.sub.2CH.sub.2                                         574  2-CH.sub.3       CH.sub.2CH.sub.2                                         575  3-CH.sub.3       CH.sub.2CH.sub.2                                         576  4-CH.sub.3       CH.sub.2CH.sub.2                                         577  2,3-(CH.sub.3).sub.2                                                                            CH.sub.2CH.sub.2                                         578  2,4-(CH.sub.3).sub.2                                                                            CH.sub.2CH.sub.2                                         579  2,5-(CH.sub.3).sub.2                                                                            CH.sub.2CH.sub.2                                         580  2,6-(CH.sub.3).sub.2                                                                            CH.sub.2CH.sub.2                                         581  3,4-(CH.sub.3).sub.2                                                                            CH.sub.2CH.sub.2                                         582  3,5-(CH.sub.3).sub.2                                                                            CH.sub.2CH.sub.2                                         583  2,3,4-(CH.sub.3).sub.3                                                                          CH.sub.2CH.sub.2                                         584  2,3,5-(CH.sub.3).sub.3                                                                          CH.sub.2CH.sub.2                                         585  2,4,5-(CH.sub.3).sub.3                                                                          CH.sub.2CH.sub.2                                         587  2,4,6-(CH.sub.3).sub.3                                                                          CH.sub.2CH.sub.2                                         588  3,4,5-(CH.sub.3).sub.3                                                                          CH.sub.2CH.sub.2                                         589  2,3,4,6-(CH.sub.3).sub.4                                                                        CH.sub.2CH.sub.2                                         590  2,3,5,6-(CH.sub.3).sub.4                                                                        CH.sub.2CH.sub.2                                         591  2,3,4,5,6-(CH.sub.3).sub.5                                                                      CH.sub.2CH.sub.2                                         592  2-C.sub.2 H.sub.5                                                                               CH.sub.2CH.sub.2                                         593  3-C.sub.2 H.sub.5                                                                               CH.sub.2CH.sub.2                                         594  4-C.sub.2 H.sub.5                                                                               CH.sub.2CH.sub.2                                         595  2,4-(C.sub.2 H.sub.5).sub.2                                                                     CH.sub.2CH.sub.2                                         596  2,6-(C.sub.2 H.sub.5).sub.2                                                                     CH.sub.2CH.sub.2                                         597  3,5-(C.sub.2 H.sub.5).sub.2                                                                     CH.sub.2CH.sub.2                                         598  2,4,6-(C.sub.2 H.sub.5).sub.3                                                                   CH.sub.2CH.sub.2                                         599  2-n-C.sub.3 H.sub.7                                                                             CH.sub.2CH.sub.2                                         600  3-n-C.sub.3 H.sub.7                                                                             CH.sub.2CH.sub.2                                         601  4-n-C.sub.3 H.sub.7                                                                             CH.sub.2CH.sub.2                                         602  2-i-C.sub.3 H.sub.7                                                                             CH.sub.2CH.sub.2                                         603  3-i-C.sub.3 H.sub.7                                                                             CH.sub.2CH.sub.2                                         604  4-i-C.sub.3 H.sub.7                                                                             CH.sub.2CH.sub.2                                         605  2,4-(i-C.sub.3 H.sub.7).sub.2                                                                   CH.sub.2CH.sub.2                                         606  2,6-(i-C.sub.3 H.sub.7).sub.2                                                                   CH.sub.2CH.sub.2                                         607  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 CH.sub. 2CH.sub.2                                        608  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 CH.sub.2CH.sub.2                                         609  2-s-C.sub.4 H.sub.9                                                                             CH.sub.2CH.sub.2                                         610  3-s-C.sub.4 H.sub.9                                                                             CH.sub.2CH.sub.2                                         611  4-s-C.sub.4 H.sub.9                                                                             CH.sub.2CH.sub.2                                         612  2-t-C.sub.4 H.sub.9                                                                             CH.sub.2CH.sub.2                                         613  3-t-C.sub.4 H.sub.9                                                                             CH.sub.2CH.sub.2                                         614  4-t-C.sub.4 H.sub.9                                                                             CH.sub.2CH.sub.2                                         615  2,3-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2CH.sub.2                                         616  2,4-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2CH.sub.2                                         617  2,5-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2CH.sub.2                                         618  2,6-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2CH.sub.2                                         619  3,5-(t-C.sub.4 H.sub.9).sub.2                                                                   CH.sub.2CH.sub.2                                         620  2,4,6-(t-C.sub.4 H.sub.9).sub.3                                                                 CH.sub.2CH.sub.2                                         621  4-n-C.sub.9 H.sub.19                                                                            CH.sub.2CH.sub.2                                         622  4-n-C.sub.12 H.sub.25                                                                           CH.sub.2CH.sub.2                                         623  3-n-C.sub.15 H.sub.31                                                                           CH.sub.2CH.sub.2                                         624  4-(1,1,3,3,-tetramethylbutyl)                                                                   CH.sub.2CH.sub.2                                         625  4-(1,1,3,-trimethylbutyl)                                                                       CH.sub.2CH.sub.2                                         626  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                                                 CH.sub.2CH.sub.2                                         627  2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                                                 CH.sub.2CH.sub.2                                         628  2,6-(t-C.sub.4 H.sub.9).sub.2, 4-CH.sub.3                                                       CH.sub.2 CH.sub.2                                        629  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                                                 CH.sub.2CH.sub.2                                         630  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                                                 CH.sub.2CH.sub.2                                         631  2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 CH.sub.2CH.sub.2                                         632  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                                                 CH.sub.2CH.sub.2                                         633  3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 CH.sub.2CH.sub.2                                         634  2-i-C.sub.3 H.sub.7, 5-CH.sub.3                                                                 CH.sub.2CH.sub.2                                         635  2,4-(t-C.sub.4 H.sub.9).sub.2, 6-i-C.sub.3 H.sub.7                                              CH.sub.2CH.sub.2                                         636  2-C.sub.3 H.sub.5 (= Allyl)                                                                     CH.sub.2CH.sub.2                                         637  3-C.sub.3 H.sub.5                                                                               CH.sub.2CH.sub.2                                         638  4-C.sub.3 H.sub.5                                                                               CH.sub.2CH.sub.2                                         639  2-C.sub.3 H.sub.5, 6-CH.sub.3                                                                   CH.sub.2CH.sub.2                                         640  2-cyclo-C.sub.6 H.sub.11                                                                        CH.sub.2CH.sub.2                                         641  3-cyclo-C.sub.6 H.sub.11                                                                        CH.sub.2CH.sub.2                                         642  4-cyclo-C.sub.6 H.sub.11                                                                        CH.sub.2CH.sub.2                                         643  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                                                  CH.sub.2CH.sub.2                                         644  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                                            CH.sub.2CH.sub.2                                         645  2-CH.sub.3, 4-(1,1,3,3-tetramethylbutyl)                                                        CH.sub.2CH.sub.2                                         646  2-CH.sub.2 C.sub.6 H.sub.5                                                                      CH.sub.2CH.sub.2                                         647  3-CH.sub.2 C.sub.6 H.sub.5                                                                      CH.sub.2CH.sub.2                                         648  4-CH.sub.2 C.sub.6 H.sub.5                                                                      CH.sub.2CH.sub.2                                         649  2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                                          CH.sub.2CH.sub.2                                         650  2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                                          CH.sub.2CH.sub.2                                         651  2-C.sub.6 H.sub.5                                                                               CH.sub.2CH.sub.2                                         652  3-C.sub.6 H.sub.5                                                                               CH.sub.2CH.sub.2                                         653  4-C.sub.6 H.sub.5                                                                               CH.sub.2CH.sub.2                                         654  4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                                          CH.sub.2CH.sub.2                                         655  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                                         CH.sub.2CH.sub.2                                         656  2-Cl, 4-C.sub.6 H.sub.5                                                                         CH.sub.2CH.sub.2                                         657  2-Br, 4-C.sub.6 H.sub.5                                                                         CH.sub.2CH.sub.2                                         658  2-C.sub.6 H.sub.5, 4-Cl                                                                         CH.sub.2CH.sub.2                                         659  2-C.sub.6 H.sub.5, 4-Br                                                                         CH.sub.2CH.sub.2                                         660  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                                                CH.sub.2CH.sub.2                                         661  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                                                CH.sub.2CH.sub.2                                         662  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                                                CH.sub.2CH.sub.2                                         663  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                                                CH.sub.2CH.sub.2                                         664  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                                                  CH.sub.2CH.sub.2                                         665  2-cyclo-C.sub.6 H.sub.11, 4-Br                                                                  CH.sub.2CH.sub.2                                         666  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                                                  CH.sub.2CH.sub.2                                         667  2-Br, 4-cyclo-C.sub.6 H.sub.11                                                                  CH.sub.2CH.sub.2                                         668  2-OCH.sub.3      CH.sub.2CH.sub.2                                         669  3-OCH.sub.3      CH.sub.2CH.sub.2                                         670  4-OCH.sub.3      CH.sub.2CH.sub.2                                         671  2,4-(OCH.sub.3).sub.2                                                                           CH.sub.2CH.sub.2                                         672  2-OC.sub.2 H.sub.5                                                                              CH.sub.2CH.sub.2                                         673  3-OC.sub.2 H.sub.5                                                                              CH.sub.2CH.sub.2                                         674  4-OC.sub.2 H.sub.5                                                                              CH.sub.2CH.sub.2                                         675  2-OCH.sub.2 C.sub.6 H.sub.5                                                                     CH.sub.2CH.sub.2                                         676  3-OCH.sub.2 C.sub.6 H.sub.5                                                                     CH.sub.2CH.sub.2                                         677  4-OCH.sub.2 C.sub.6 H.sub.5                                                                     CH.sub.2CH.sub.2                                         678  2-O-t-C.sub.4 H.sub.9                                                                           CH.sub.2CH.sub.2                                         679  3-O-t-C.sub.4 H.sub.9                                                                           CH.sub.2CH.sub.2                                         680  4-O-t-C.sub.4 H.sub.9                                                                           CH.sub.2CH.sub.2                                         681  2-OC.sub.6 H.sub.5                                                                              CH.sub.2CH.sub.2                                         682  3-OC.sub.6 H.sub.5                                                                              CH.sub.2CH.sub.2                                         683  4-OC.sub.6 H.sub.5                                                                              CH.sub.2CH.sub.2                                         684  2-CF.sub. 3      CH.sub.2CH.sub.2                                         685  3-CF.sub.3       CH.sub.2CH.sub.2                                         686  4-CF.sub.3       CH.sub.2CH.sub.2                                         687  2-OCF.sub.3      CH.sub.2CH.sub.2                                         688  3-OCF.sub.3      CH.sub.2CH.sub.2                                         689  4-OCF.sub.3      CH.sub.2CH.sub.2                                         690  3-OCH.sub.2 CHF.sub.2                                                                           CH.sub.2CH.sub.2                                         691  3-OCF.sub.2 CHF.sub.2                                                                           CH.sub.2CH.sub.2                                         692  3-OC.sub.2 F.sub.5                                                                              CH.sub.2CH.sub.2                                         693  2-NO.sub.2       CH.sub.2CH.sub.2                                         694  3-NO.sub.2       CH.sub.2CH.sub.2                                         695  4-NO.sub.2       CH.sub.2CH.sub.2                                         696  2-CN             CH.sub.2CH.sub.2                                         697  3-CN             CH.sub.2CH.sub.2                                         698  4-CN             CH.sub.2CH.sub.2                                         699  2-CH.sub.3, 3-Cl CH.sub.2CH.sub.2                                         700  2-CH.sub.3, 4-Cl CH.sub.2CH.sub.2                                         701  2-CH.sub.3, 5-Cl CH.sub.2CH.sub.2                                         702  2-CH.sub.3, 6-Cl CH.sub.2CH.sub.2                                         703  2-CH.sub.3, 3-F  CH.sub.2CH.sub.2                                         704  2-CH.sub.3, 4-F  CH.sub.2CH.sub.2                                         705  2-CH.sub.3, 5-F  CH.sub.2CH.sub.2                                         706  2-CH.sub.3, 6-F  CH.sub.2CH.sub.2                                         707  2-CH.sub.3, 3-Br CH.sub.2CH.sub.2                                         708  2-CH.sub.3, 4-Br CH.sub.2CH.sub.2                                         709  2-CH.sub.3, 5-Br CH.sub.2CH.sub.2                                         710  2-CH.sub.3, 6-Br CH.sub.2CH.sub.2                                         711  2-Cl, 3-CH.sub.3 CH.sub.2CH.sub.2                                         712  2-Cl, 4-CH.sub.3 CH.sub.2CH.sub.2                                         713  2-Cl, 5-CH.sub.3 CH.sub.2CH.sub.2                                         714  2-F, 3-CH.sub.3  CH.sub.2CH.sub.2                                         715  2-F, 4-CH.sub.3  CH.sub.2CH.sub.2                                         716  2-F, 5-CH.sub.3  CH.sub.2CH.sub.2                                         717  2-Br, 3-CH.sub.3 CH.sub.2CH.sub.2                                         718  2-Br, 4-CH.sub.3 CH.sub.2CH.sub.2                                         719  2-Br, 5-CH.sub.3 CH.sub.2CH.sub.2                                         720  3-CH.sub.3, 4-Cl CH.sub.2CH.sub.2                                         721  3-CH.sub.3, 5-Cl CH.sub.2CH.sub.2                                         722  3-CH.sub.3, 4-F  CH.sub.2CH.sub.2                                         723  3-CH.sub.3, 5-F  CH.sub.2CH.sub.2                                         724  3-CH.sub.3, 4-Br CH.sub.2CH.sub.2                                         725  3-CH.sub.3, 5-Br CH.sub.2CH.sub.2                                         726  3-F, 4-CH.sub.3  CH.sub.2CH.sub.2                                         727  3-Cl, 4-CH.sub.3 CH.sub.2CH.sub.2                                         728  3-Br, 4-CH.sub.3 CH.sub.2CH.sub.2                                         729  2-Cl, 4,5-(CH.sub.3).sub.2                                                                      CH.sub.2CH.sub.2                                         730  2-Br, 4,5-(CH.sub.3).sub.2                                                                      CH.sub.2CH.sub.2                                         731  2-Cl, 3,5-(CH.sub.3).sub.2                                                                      CH.sub.2CH.sub.2                                         732  2-Br, 3,5-(CH.sub.3).sub.2                                                                      CH.sub.2CH.sub.2                                         733  2,6-Cl.sub.2, 4-CH.sub.3                                                                        CH.sub.2CH.sub.2                                         734  2,6-F.sub.2, 4-CH.sub.3                                                                         CH.sub.2CH.sub.2                                         735  2,6-Br.sub.2, 4-CH.sub.3                                                                        CH.sub.2CH.sub.2                                         736  2,4-Cl.sub.2, 6-CH.sub.3                                                                        CH.sub.2CH.sub.2                                         737  2,4-F.sub.2, 6-CH.sub.3                                                                         CH.sub.2CH.sub.2                                         738  2,4-Br.sub.2, 6-CH.sub.3                                                                        CH.sub.2CH.sub.2                                         739  2,6-(CH.sub.3).sub.2, 4-F                                                                       CH.sub.2CH.sub.2                                         740  2,6-(CH.sub.3).sub.2, 4-Cl                                                                      CH.sub.2CH.sub.2                                         741  2,6-(CH.sub.3).sub.2, 4-Br                                                                      CH.sub.2CH.sub.2                                         742  3,5-(CH.sub.3).sub.2, 4-F                                                                       CH.sub.2CH.sub.2                                         743  3,5-(CH.sub.3).sub.2, 4-Cl                                                                      CH.sub.2CH.sub.2                                         744  3,5-(CH.sub.3).sub.2, 4-Br                                                                      CH.sub.2CH.sub.2                                         745  2,3,6-(CH.sub.3).sub.3, 4-F                                                                     CH.sub.2CH.sub.2                                         746  2,3,6-(CH.sub.3).sub.3, 4-Cl                                                                    CH.sub.2CH.sub.2                                         747  2,3,6-(CH.sub.3).sub.3, 4-Br                                                                    CH.sub.2CH.sub.2                                         748  2,4-(CH.sub.3).sub.2, 6-F                                                                       CH.sub.2CH.sub.2                                         749  2,4-(CH.sub.3).sub.2, 6-Cl                                                                      CH.sub.2CH.sub.2                                         750  2,4-(CH.sub.3).sub.2, 6-Br                                                                      CH.sub.2CH.sub.2                                         751  2-i-C.sub.3 H.sub. 7, 4-Cl, 5-CH.sub.3                                                          CH.sub.2CH.sub.2                                         752  2-CH.sub.3, 4-Cl, 5-i-C.sub.3 H.sub.7                                                           CH.sub.2CH.sub.2                                         753  2-Cl, 3-i-C.sub.3 H.sub.7                                                                       CH.sub.2CH.sub.2                                         754  2-Cl, 4-i-C.sub.3 H.sub.7                                                                       CH.sub.2CH.sub.2                                         755  2-Cl, 4-NO.sub.2 CH.sub.2CH.sub.2                                         756  2-NO.sub.2, 4-Cl CH.sub.2CH.sub.2                                         757  2-OCH.sub.3, 5-NO.sub.2                                                                         CH.sub.2CH.sub.2                                         758  2,4-Cl.sub.2, 5-NO.sub.2                                                                        CH.sub.2CH.sub.2                                         759  2,4-Cl.sub.2, 6-NO.sub.2                                                                        CH.sub.2CH.sub.2                                         760  2,6-Cl.sub.2, 4-NO.sub.2                                                                        CH.sub.2CH.sub.2                                         761  2,6-Br.sub.2, 4-NO.sub.2                                                                        CH.sub.2CH.sub.2                                         762  2,6-I.sub.2, 4-NO.sub.2                                                                         CH.sub.2CH.sub.2                                         763  H                CHCH                                                     764  2-F              CHCH                                                     765  3-F              CHCH                                                     766  4-F              CHCH                                                     767  2,3-F.sub.2      CHCH                                                     768  2,4-F.sub.2      CHCH                                                     769  2,4,6-F.sub.3    CHCH                                                     770  2,3,4,5,6-F.sub.5                                                                               CHCH                                                     771  2-Cl             CHCH                                                     772  3-Cl             CHCH                                                     773  4-Cl             CHCH                                                     774  2,3-Cl.sub.2     CHCH                                                     775  2,4-Cl.sub.2     CHCH                                                     776  2,5-Cl.sub.2     CHCH                                                     777  2,6-Cl.sub.2     CHCH                                                     778  3,4-Cl.sub.2     CHCH                                                     779  3,5-Cl.sub.2     CHCH                                                     780  2,3,4-Cl.sub.3   CHCH                                                     781  2,3,5-Cl.sub.3   CHCH                                                     782  2,3,6-Cl.sub.3   CHCH                                                     783  2,4,5-Cl.sub.3   CHCH                                                     784  2,4,6-Cl.sub.3   CHCH                                                     785  3,4,5-Cl.sub.3   CHCH                                                     786  2,3,4,6-Cl.sub.4 CHCH                                                     787  2,3,5,6-Cl.sub.4 CHCH                                                     788  2,3,4,5,6-Cl.sub.5                                                                              CHCH                                                     789  2-Br             CHCH                                                     790  3-Br             CHCH                                                     791  4-Br             CHCH                                                     792  2,4-Br.sub.2     CHCH                                                     793  2,5-Br.sub.2     CHCH                                                     794  2,6-Br.sub.2     CHCH                                                     795  2,4,6-Br.sub.3   CHCH                                                     796  2,3,4,5,6-Br.sub.5                                                                              CHCH                                                     797  2-I              CHCH                                                     798  3-I              CHCH                                                     799  4-I              CHCH                                                     800  2,4-I.sub.2      CHCH                                                     801  2-Cl, 3-F        CHCH                                                     802  2-Cl, 4-F        CHCH                                                     803  2-Cl, 5-F        CHCH                                                     804  2-Cl, 6-F        CHCH                                                     805  2-Cl, 3-Br       CHCH                                                     806  2-Cl, 4-Br       CHCH                                                     807  2-Cl, 5-Br       CHCH                                                     808  2-Cl, 6-Br       CHCH                                                     809  2-Br, 3-Cl       CHCH                                                     810  2-Br, 4-Cl       CHCH                                                     811  2-Br, 5-Cl       CHCH                                                     812  2-Br, 3-F        CHCH                                                     813  2-Br, 4-F        CHCH                                                     814  2-Br, 5-F        CHCH                                                     815  2-Br, 6-F        CHCH                                                     816  2-F, 3-Cl        CHCH                                                     817  2-F, 4-Cl        CHCH                                                     818  2-F, 5-Cl        CHCH                                                     819  3-Cl, 4-F        CHCH                                                     820  3-Cl, 5-F        CHCH                                                     821  3-Cl, 4-Br       CH CH                                                    822  3-Cl, 5-Br       CHCH                                                     823  3-F, 4-Cl        CHCH                                                     824  3-F, 4-Br        CHCH                                                     825  3-Br, 4-Cl       CHCH                                                     826  3-Br, 4-F        CHCH                                                     827  2,6-Cl.sub.2, 4-Br                                                                              CHCH                                                     828  2-CH.sub.3       CHCH                                                     829  3-CH.sub.3       CHCH                                                     830  4-CH.sub.3       CHCH                                                     831  2,3-(CH.sub.3).sub.2                                                                            CHCH                                                     832  2,4-(CH.sub.3).sub.2                                                                            CHCH                                                     833  2,5-(CH.sub.3).sub.3                                                                            CHCH                                                     834  2,6-(CH.sub.3).sub.2                                                                            CHCH                                                     835  3,4-(CH.sub.3).sub.2                                                                            CHCH                                                     836  3,5-(CH.sub.3).sub.2                                                                            CHCH                                                     837  2,3,4-(CH.sub.3).sub.3                                                                          CHCH                                                     838  2,3,5-(CH.sub.3).sub.3                                                                          CHCH                                                     839  2,3,6-(CH.sub.3).sub.3                                                                          CHCH                                                     840  2,4,5-(CH.sub.3).sub.3                                                                          CHCH                                                     841  2,4,6-(CH.sub.3).sub.3                                                                          CHCH                                                     842  3,4,5-(CH.sub.3).sub.3                                                                          CHCH                                                     843  2,3,4,6-(CH.sub.3).sub.4                                                                        CHCH                                                     844  2,3,5,6-(CH.sub.3).sub.4                                                                        CHCH                                                     845  2,3,4,5,6-(CH.sub.3).sub.5                                                                      CHCH                                                     846  2-C.sub.2 H.sub.5                                                                               CHCH                                                     847  3-C.sub.2 H.sub.5                                                                               CHCH                                                     848  4-C.sub.2 H.sub.5                                                                               CHCH                                                     849  2,4-(C.sub.2 H.sub.5).sub.2                                                                     CHCH                                                     850  2,6-(C.sub.2 H.sub.5).sub.2                                                                     CHCH                                                     851  3,5-(C.sub.2 H.sub.5).sub.2                                                                     CH CH                                                    852  2,4,6-(C.sub.2 H.sub.5).sub.3                                                                   CHCH                                                     853  2-n-C.sub.3 H.sub.7                                                                             CHCH                                                     854  3-n-C.sub.3 H.sub.7                                                                             CHCH                                                     855  4-n-C.sub.3 H.sub.7                                                                             CHCH                                                     856  2-i-C.sub.2 H.sub.7                                                                             CHCH                                                     857  3-i-C.sub.2 H.sub.7                                                                             CHCH                                                     858  4-i-C.sub.3 H.sub.7                                                                             CHCH                                                     859  2,4-(i-C.sub.3 H.sub.7).sub.2                                                                   CHCH                                                     860  2,6-(i-C.sub.3 H.sub.7).sub.2                                                                   CHCH                                                     861  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 CHCH                                                     862  2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 CHCH                                                     863  2-s-C.sub.4 H.sub.9                                                                             CHCH                                                     864  3-s-C.sub.4 H.sub.9                                                                             CHCH                                                     865  4-s-C.sub.4 H.sub.9                                                                             CHCH                                                     866  2-t-C.sub.4 H.sub.9                                                                             CHCH                                                     867  3-t-C.sub.4 H.sub.9                                                                             CHCH                                                     868  4-t-C.sub.4 H.sub.9                                                                             CHCH                                                     869  2,3-(t-C.sub.4 H.sub.9).sub.2                                                                   CHCH                                                     870  2,4-(t-C.sub.4 H.sub.9).sub.2                                                                   CHCH                                                     871  2,5-(t-C.sub.4 H.sub.9).sub.2                                                                   CHCH                                                     872  2,6-(t-C.sub.4 H.sub.9).sub.2                                                                   CHCH                                                     873  3,5-(t-C.sub.4 H.sub.9).sub.2                                                                   CHCH                                                     874  2,4,6-(t-C.sub.4 H.sub.9).sub.3                                                                 CHCH                                                     875  4-n-C.sub.9 H.sub.19                                                                            CHCH                                                     876  4-n-C.sub.12 H.sub.25                                                                           CHCH                                                     877  3-n-C.sub. 15 H.sub.31                                                                          CHCH                                                     878  4-(1,1,3,3,-tetramethylbutyl)                                                                   CHCH                                                     879  4-(1,1,3,-trimethylbutyl)                                                                       CHCH                                                     880  2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                                                 CHCH                                                     881  2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                                                 CHCH                                                     882  2,6-(t-C.sub.4 H.sub.9).sub.2, 4-CH.sub.3                                                       CHCH                                                     883  2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                                                 CHCH                                                     884  2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                                                 CHCH                                                     885  2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 CHCH                                                     886  2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                                                 CHCH                                                     887  3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 CHCH                                                     888  2-i-C.sub.3 H.sub.7, 5-CH.sub.3                                                                 CHCH                                                     889  2,4-(t-C.sub.4 H.sub.9).sub.2, 6-i-C.sub.3 H.sub.7                                              CHCH                                                     890  2-C.sub.3 H.sub.5 (= allyl)                                                                     CHCH                                                     891  3-C.sub.3 H.sub.5                                                                               CHCH                                                     892  4-C.sub.3 H.sub.5                                                                               CHCH                                                     893  2-C.sub.3 H.sub.5, 6-CH.sub.3                                                                   CHCH                                                     894  2-cyclo-C.sub.6 H.sub.11                                                                        CHCH                                                     895  3-cyclo-C.sub.6 H.sub.11                                                                        CHCH                                                     896  4-cyclo-C.sub.6 H.sub.11                                                                        CHCH                                                     897  2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                                                  CHCH                                                     898  2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                                            CHCH                                                     899  2-CH.sub.3 , 4-(1,1,3,3-tetramethylbutyl)                                                       CHCH                                                     900  2-CH.sub.2 C.sub.6 H.sub.5                                                                      CHCH                                                     901  3-CH.sub.2 C.sub.6 H.sub.5                                                                      CHCH                                                     902  4-CH.sub.2 C.sub.6 H.sub.5                                                                      CHCH                                                     903  2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                                          CHCH                                                     904  2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                                          CHCH                                                     905  2-C.sub.6 H.sub.5                                                                               CHCH                                                     906  3-C.sub.6 H.sub.5                                                                               CHCH                                                     907  4-C.sub.6 H.sub.5                                                                               CHCH                                                     908  4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                                          CHCH                                                     909  4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                                         CHCH                                                     910  2-Cl, 4-C.sub.6 H.sub.5                                                                         CHCH                                                     911  2-Br, 4-C.sub.6 H.sub.5                                                                         CHCH                                                     912  2-C.sub.6 H.sub.5, 4-Cl                                                                         CHCH                                                     913  2-C.sub.6 H.sub.5, 4-Br                                                                         CHCH                                                     914  2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                                                CHCH                                                     915  2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                                                CHCH                                                     916  2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                                                CHCH                                                     917  2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                                                CHCH                                                     918  2-cyclo-C.sub.6 H.sub.11, 4-Cl                                                                  CHCH                                                     919  2-cyclo-C.sub.6 H.sub.11, 4-Br                                                                  CHCH                                                     920  2-Cl, 4-cyclo-C.sub.6 H.sub.11                                                                  CHCH                                                     921  2-Br, 4-cyclo-C.sub.6 H.sub.11                                                                  CHCH                                                     922  2-OCH.sub.3      CHCH                                                     923  3-OCH.sub.3      CHCH                                                     924  4-OCH.sub.3      CHCH                                                     925  2,4-(OCH.sub.3).sub.2                                                                           CHCH                                                     926  2-OC.sub.2 H.sub.5                                                                              CHCH                                                     927  3-OC.sub.2 H.sub.5                                                                              CHCH                                                     928  4-OC.sub.2 H.sub.5                                                                              CHCH                                                     929  2-OCH.sub.2 C.sub.6 H.sub.5                                                                     CHCH                                                     930  3-OCH.sub.2 C.sub.6 H.sub.5                                                                     CHCH                                                     931  4-OCH.sub.2 C.sub.6 H.sub.5                                                                     CHCH                                                     932  2-O-t-C.sub.4 H.sub.9                                                                           CHCH                                                     933  3-O-t-C.sub.4 H.sub.9                                                                           CHCH                                                     934  4-O-t-C.sub.4 H.sub.9                                                                           CHCH                                                     935  2-OC.sub.6 H.sub.5                                                                              CHCH                                                     936  3-OC.sub.6 H.sub.5                                                                              CHCH                                                     937  4-OC.sub.6 H.sub.5                                                                              CHCH                                                     938  2-CF.sub.3       CHCH                                                     939  3-CF.sub.3       CHCH                                                     940  4-CF.sub.3       CHCH                                                     941  2-OCF.sub.3      CHCH                                                     942  3-OCF.sub.3      CHCH                                                     943  4-OCF.sub.3      CHCH                                                     944  3-OCH.sub.2 CHF.sub.2                                                                           CHCH                                                     945  3-OCF.sub.2 CHF.sub.2                                                                           CHCH                                                     946  3-OC.sub.2 H.sub.5                                                                              CHCH                                                     947  2-NO.sub.2       CHCH                                                     948  3-NO.sub.2       CHCH                                                     949  4-NO.sub.2       CHCH                                                     950  2-CN             CHCH                                                     951  3-CN             CHCH                                                     952  4-CN             CHCH                                                     953  2-CH.sub.3, 3-Cl CHCH                                                     954  2-CH.sub.3, 4-Cl CHCH                                                     955  2-CH.sub.3, 5-Cl CHCH                                                     956  2-CH.sub.3, 6-Cl CHCH                                                     957  2-CH.sub.3, 3-F  CHCH                                                     958  2-CH.sub.3, 4-F  CHCH                                                     959  2-CH.sub.3, 5-F  CHCH                                                     960  2-CH.sub.3, 6-F  CHCH                                                     961  2-CH.sub.3, 3-Br CHCH                                                     962  2-CH.sub.3, 4-Br CHCH                                                     963  2-CH.sub.3, 5-Br CHCH                                                     964  2-CH.sub.3, 6-Br CHCH                                                     965  2-Cl, 3-CH.sub.3 CHCH                                                     966  2-Cl, 4-CH.sub.3 CHCH                                                     967  2-Cl, 5-CH.sub.3 CHCH                                                     968  2-F, 3-CH.sub.3  CHCH                                                     969  2-F, 4-CH.sub.3  CHCH                                                     970  2-F, 5-CH.sub.3  CHCH                                                     971  2-Br, 3-CH.sub.3 CHCH                                                     972  2-Br, 4-CH.sub.3 CHCH                                                     973  2-Br, 5-CH.sub.3 CHCH                                                     974  3-CH.sub.3, 4-Cl CHCH                                                     975  3-CH.sub.3, 5-Cl CHCH                                                     976  3-CH.sub.3, 4-F  CHCH                                                     977  3-CH.sub.3, 5-F  CHCH                                                     978  3-CH.sub.3, 4-Br CHCH                                                     979  3-CH.sub.3, 5-Br CHCH                                                     980  3-F, 4-CH.sub.3  CHCH                                                     981  3-Cl, 4-CH.sub.3 CHCH                                                     982  3-Br, 4-CH.sub.3 CHCH                                                     983  2-Cl, 4,5-(CH.sub.3).sub.2                                                                      CHCH                                                     984  2-Br, 4,5-(CH.sub.3).sub.2                                                                      CHCH                                                     985  2-Cl, 3,5-(CH.sub.3).sub.2                                                                      CHCH                                                     986  2-Br, 3,5-(CH.sub.3).sub.2                                                                      CHCH                                                     987  2,6-Cl.sub.2, 4-CH.sub.3                                                                        CHCH                                                     988  2,6-F.sub.2, 4-CH.sub.3                                                                         CHCH                                                     989  2,6-Br.sub.2, 4-CH.sub.3                                                                        CHCH                                                     990  2,4-Cl.sub.2, 6-CH.sub.3                                                                        CHCH                                                     991  2,4-F.sub.2, 6-CH.sub.3                                                                         CHCH                                                     992  2,4-Br.sub.2, 6-CH.sub.3                                                                        CHCH                                                     993  2,6-(CH.sub.3).sub.2, 4-F                                                                       CHCH                                                     994  2,6-(CH.sub.3).sub.2, 4-Cl                                                                      CHCH                                                     995  2,6-(CH.sub.3).sub.2, 4-Br                                                                      CHCH                                                     996  3,5-(CH.sub.3).sub.2, 4-F                                                                       CHCH                                                     997  3,5-(CH.sub.3).sub.2, 4-Cl                                                                      CHCH                                                     998  3,5-(CH.sub.3).sub.2, 4-Br                                                                      CHCH                                                     999  2,3,6-(CH.sub.3).sub.3, 4-F                                                                     CHCH                                                     1000 2,3,6-(CH.sub.3).sub.3, 4-Cl                                                                    CHCH                                                     1001 2,3,6-(CH.sub.3).sub.3, 4-Br                                                                    CHCH                                                     1002 2,4-(CH.sub.2).sub.2, 6-F                                                                       CHCH                                                     1003 2,4-(CH.sub.3).sub.2, 6-Cl                                                                      CHCH                                                     1004 2,4-(CH.sub.3).sub.2, 6-Br                                                                      CHCH                                                     1005 2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                                           CHCH                                                     1006 2-CH.sub.3 , 4-Cl, 5-i-C.sub.3 H.sub.7                                                          CHCH                                                     1007 2-Cl, 3-i-C.sub.3 H.sub.7                                                                       CHCH                                                     1008 2-Cl, 4-i-C.sub.3 H.sub.7                                                                       CHCH                                                     1009 2-Cl, 4-NO.sub.2 CHCH                                                     1010 2-NO.sub.2, 4-Cl CHCH                                                     1011 2-OCH.sub.3, 5-NO.sub.2                                                                         CHCH                                                     1012 2,4-Cl.sub.2, 5-NO.sub.2                                                                        CHCH                                                     1013 2,4-Cl.sub.2, 6-NO.sub.2                                                                        CHCH                                                     1014 2,6-Cl.sub.2, 4-NO.sub.2                                                                        CHCH                                                     1015 2,6-Br.sub.2, 4-NO.sub.2                                                                        CHCH                                                     1016 2,6-I.sub.2, 4-NO.sub.2                                                                         CHCH                                                     1017 H                SCH.sub.2                                                1018 2-F              SCH.sub.2                                                1019 3-F              SCH.sub.2                                                1020 4-F              SCH.sub.2                                                1021 2,3-F.sub.2      SCH.sub.2                                                1022 2,4-F.sub.2      SCH.sub.2                                                1023 2,4,6-F.sub.3    SCH.sub.2                                                1024 2,3,4,5,6-F.sub.5                                                                               SCH.sub.2                                                1025 2-Cl             SCH.sub.2                                                1026 3-Cl             SCH.sub.2                                                1027 4-Cl             SCH.sub.2                                                1028 2,3-Cl.sub.2     SCH.sub.2                                                1029 2,4-Cl.sub.2     SCH.sub.2                                                1030 2,5-Cl.sub.2     SCH.sub.2                                                1031 2,6-Cl.sub.2     SCH.sub.2                                                1032 3,4-Cl.sub.2     SCH.sub.2                                                1033 3,5-Cl.sub.2     SCH.sub.2                                                1034 2,3,4-Cl.sub.3   SCH.sub.2                                                1035 2,3,5-Cl.sub.3   SCH.sub.2                                                1036 2,3,6-Cl.sub.3   SCH.sub.2                                                1037 2,4,5-Cl.sub.3   SCH.sub.2                                                1038 2,4,6-Cl.sub.3   SCH.sub.2                                                1039 3,4,5-Cl.sub.3   SCH.sub.2                                                1040 2,3,4,6-Cl.sub.4 SCH.sub.2                                                1041 2,3,5,6,-Cl.sub. 4                                                                              SCH.sub.2                                                1042 2,3,4,5,6-Cl.sub.5                                                                              SCH.sub.2                                                1043 2-Br             SCH.sub.2                                                1044 3-Br             SCH.sub.2                                                1045 4-Br             SCH.sub.2                                                1046 2,4-Br.sub.2     SCH.sub.2                                                1047 2,5-Br.sub.2     SCH.sub.2                                                1048 2,6-Br.sub.2     SCH.sub.2                                                1049 2,4,6-Br.sub.3   SCH.sub.2                                                1050 2,3,4,5,6-Br.sub.5                                                                              SCH.sub.2                                                1051 2-I              SCH.sub.2                                                1052 3-I              SCH.sub.2                                                1053 4-I              SCH.sub.2                                                1054 2,4-I.sub.2      SCH.sub.2                                                1055 2-Cl, 3-F        SCH.sub.2                                                1056 2-Cl, 4-F        SCH.sub.2                                                1057 2-Cl, 5-F        SCH.sub.2                                                1058 2-Cl, 6-F        SCH.sub.2                                                1059 2-Cl, 3-Br       SCH.sub.2                                                1060 2-Cl, 4-Br       SCH.sub.2                                                1061 2-Cl, 5-Br       SCH.sub.2                                                1062 2-Cl, 6-Br       SCH.sub.2                                                1063 2-Br, 3-Cl       SCH.sub.2                                                1064 2-Br, 4-Cl       SCH.sub.2                                                1065 2-Br, 5-Cl       SCH.sub.2                                                1066 2-Br, 3-F        SCH.sub.2                                                1067 2-Br, 4-F        SCH.sub.2                                                1068 2-Br, 5-F        SCH.sub.2                                                1069 2-Br, 6-F        SCH.sub.2                                                1070 2-F, 3-Cl        SCH.sub.2                                                1071 2-F, 4-Cl        SCH.sub.2                                                1072 2-F, 5-Cl        SCH.sub.2                                                1073 3-Cl, 4-F        SCH.sub.2                                                1074 3-Cl, 5-F        SCH.sub.2                                                1075 3-Cl, 4-Br       SCH.sub.2                                                1076 3-Cl, 5-Br       SCH.sub.2                                                1077 3-F, 4-Cl        SCH.sub.2                                                1078 3-F, 4-Br        SCH.sub.2                                                1079 3-Br, 4-Cl       SCH.sub.2                                                1080 3-Br, 4-F        SCH.sub.2                                                1081 2,6-Cl.sub.2, 4-Br                                                                              SCH.sub.2                                                1082 2-CH.sub.3       SCH.sub.2                                                1083 3-CH.sub.3       SCH.sub.2                                                1084 4-CH.sub.3       SCH.sub.2                                                1085 2,3-(CH.sub.3).sub.2                                                                            SCH.sub.2                                                1086 2,4-(CH.sub.3).sub.2                                                                            SCH.sub.2                                                1087 2,5-(CH.sub.3).sub.2                                                                            SCH.sub.2                                                1088 2,6-(CH.sub.3).sub.2                                                                            SCH.sub.2                                                1089 3,4-(CH.sub.3).sub.2                                                                            SCH.sub.2                                                1090 3,5-(CH.sub.3).sub.2                                                                            SCH.sub.2                                                1091 2,3,4-(CH.sub.3).sub.3                                                                          SCH.sub.2                                                1092 2,3,5-(CH.sub.3).sub.3                                                                          SCH.sub.2                                                1093 2,3,6-(CH.sub.3).sub.3                                                                          SCH.sub.2                                                1094 2,4,5-(CH.sub.3).sub.3                                                                          SCH.sub.2                                                1095 2,4,6-(CH.sub.3).sub.3                                                                          SCH.sub.2                                                1096 3,4,5-(CH.sub.3).sub.3                                                                          SCH.sub.2                                                1097 2,3,4,6-(CH.sub.3).sub.4                                                                        SCH.sub.2                                                1098 2,3,5,6-(CH.sub.3).sub.4                                                                        SCH.sub.2                                                1099 2,3,4,5,6-(CH.sub.3).sub.5                                                                      SCH.sub.2                                                1100 2-C.sub.2 H.sub.5                                                                               SCH.sub.2                                                1101 3-C.sub.2 H.sub.5                                                                               SCH.sub.2                                                1102 4-C.sub.2 H.sub.5                                                                               SCH.sub.2                                                1103 2,4-(C.sub.2 H.sub.5).sub.2                                                                     SCH.sub.2                                                1104 2,6-(C.sub.2 H.sub.5).sub.2                                                                     SCH.sub.2                                                1105 3,5-(C.sub.2 H.sub.5).sub.2                                                                     SCH.sub.2                                                1106 2,4,6-(C.sub.2 H.sub.5).sub.3                                                                   SCH.sub.2                                                1107 2-n-C.sub.3 H.sub.7                                                                             SCH.sub.2                                                1108 3-n-C.sub.3 H.sub.7                                                                             SCH.sub.2                                                1109 4-n-C.sub.3 H.sub.7                                                                             SCH.sub.2                                                1110 2-i-C.sub.2 H.sub.7                                                                             SCH.sub.2                                                1111 3-i-C.sub.2 H.sub.7                                                                             SCH.sub.2                                                1112 4-i-C.sub.3 H.sub.7                                                                             SCH.sub.2                                                1113 2,4-(i-C.sub.3 H.sub.7).sub.2                                                                   SCH.sub.2                                                1114 2,6-(i-C.sub.3 H.sub.7).sub.2                                                                   SCH.sub.2                                                1115 3,5-(i-C.sub.3 H.sub.7).sub.2                                                                   SCH.sub.2                                                1116 2,4,6-(i-C.sub.3 H.sub.7).sub.3                                                                 SCH.sub.2                                                1117 2-s-C.sub.4 H.sub.9                                                                             SCH.sub.2                                                1118 3-s-C.sub.4 H.sub.9                                                                             SCH.sub.2                                                1119 4-s-C.sub.4 H.sub.9                                                                             SCH.sub.2                                                1120 2-t-C.sub.4 H.sub.9                                                                             SCH.sub.2                                                1121 3-t-C.sub.4 H.sub.9                                                                             SCH.sub.2                                                1122 4-t-C.sub.4 H.sub.9                                                                             SCH.sub.2                                                1123 2,3-(t-C.sub.4 H.sub.9).sub.2                                                                   SCH.sub.2                                                1124 2,4-(t-C.sub.4 H.sub.9).sub.2                                                                   SCH.sub.2                                                1125 2,5-(t-C.sub.4 H.sub.9).sub.2                                                                   SCH.sub.2                                                1126 2,6-(t-C.sub.4 H.sub.9).sub.2                                                                   SCH.sub.2                                                1127 3,5-(t-C.sub.4 H.sub.9).sub.2                                                                   SCH.sub.2                                                1128 2,4,6-(t-C.sub.4 H.sub.9).sub.3                                                                 SCH.sub.2                                                1129 4-n-C.sub.9 H.sub.19                                                                            SCH.sub.2                                                1130 4-n-C.sub.12 H.sub.25                                                                           SCH.sub.2                                                1131 3-n-C.sub.15 H.sub.31                                                                           SCH.sub.2                                                1132 4-(1,1,3,3,-tetramethylbutyl)                                                                   SCH.sub.2                                                1133 4-(1,1,3,-tetramethylbutyl)                                                                     SCH.sub.2                                                1134 2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                                                 SCH.sub.2                                                1135 2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                                                 SCH.sub.2                                                1136 2,6-(t-C.sub.4 H.sub.9).sub.2, 4-CH.sub.3                                                       SCH.sub.2                                                1137 2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                                                 SCH.sub.2                                                1138 2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                                                 SCH.sub.2                                                1139 2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 SCH.sub.2                                                1140 2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                                                 SCH.sub.2                                                1141 3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 SCH.sub.2                                                1142 2-i-C.sub.3 H.sub.7, 5-CH.sub.3                                                                 SCH.sub.2                                                1143 2,4-(t-C.sub.4 H.sub.9).sub.2, 6-i-C.sub.3 H.sub.7                                              SCH.sub.2                                                1144 2-C.sub.3 H.sub.5 (= allyl)                                                                     SCH.sub.2                                                1145 3-C.sub.3 H.sub.5                                                                               SCH.sub.2                                                1146 4-C.sub.3 H.sub.5                                                                               SCH.sub.2                                                1147 2-C.sub.3 H.sub.5, 6-CH.sub.3                                                                   SCH.sub.2                                                1148 2-cyclo-C.sub.6 H.sub.11                                                                        SCH.sub.2                                                1149 3-cyclo-C.sub.6 H.sub.11                                                                        SCH.sub.2                                                1150 4-cyclo-C.sub.6 H.sub.11                                                                        SCH.sub.2                                                1151 2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                                                  SCH.sub.2                                                1152 2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                                            SCH.sub.2                                                1153 2-CH.sub.3, 4-(1,1,3,3-tetramethylbutyl)                                                        SCH.sub.2                                                1154 2-CH.sub.2 C.sub.6 H.sub.5                                                                      SCH.sub.2                                                1155 3-CH.sub.2 C.sub.6 H.sub.5                                                                      SCH.sub.2                                                1156 4-CH.sub.2 C.sub.6 H.sub.5                                                                      SCH.sub.2                                                1157 2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                                          SCH.sub.2                                                1158 2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                                          SCH.sub.2                                                1159 2-C.sub.6 H.sub.5                                                                               SCH.sub.2                                                1160 3-C.sub.6 H.sub.5                                                                               SCH.sub.2                                                1161 4-C.sub.6 H.sub.5                                                                               SCH.sub.2                                                1162 4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                                          SCH.sub.2                                                1163 4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                                         SCH.sub.2                                                1164 2-Cl, 4-C.sub.6 H.sub.5                                                                         SCH.sub.2                                                1165 2-Br, 4-C.sub.6 H.sub.5                                                                         SCH.sub.2                                                1166 2-C.sub.6 H.sub.5, 4-Cl                                                                         SCH.sub.2                                                1167 2-C.sub.6 H.sub.5, 4-Br                                                                         SCH.sub.2                                                1168 2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                                                SCH.sub.2                                                1169 2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                                                SCH.sub.2                                                1170 2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                                                SCH.sub.2                                                1171 2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                                                SCH.sub.2                                                1172 2-cyclo-C.sub.6 H.sub.11, 4-Cl                                                                  SCH.sub.2                                                1173 2-cyclo-C.sub.6 H.sub.11, 4-Br                                                                  SCH.sub.2                                                1174 2-Cl, 4-cyclo-C.sub.6 H.sub.11                                                                  SCH.sub.2                                                1175 2-Br, 4-cyclo-C.sub.6 H.sub.11                                                                  SCH.sub.2                                                1176 2-OCH.sub.3      SCH.sub.2                                                1177 3-OCH.sub.3      SCH.sub.2                                                1178 4-OCH.sub.3      SCH.sub.2                                                1179 2,4-(OCH.sub.3).sub.2                                                                           SCH.sub.2                                                1180 2-OC.sub. 2 H.sub.5                                                                             SCH.sub.2                                                1181 3-OC.sub.2 H.sub.5                                                                              SCH.sub.2                                                1182 4-OC.sub.2 H.sub.5                                                                              SCH.sub.2                                                1183 2-OCH.sub.2 C.sub.6 H.sub.5                                                                     SCH.sub.2                                                1184 3-OCH.sub.2 C.sub.6 H.sub.5                                                                     SCH.sub.2                                                1185 4-OCH.sub.2 C.sub.6 H.sub.5                                                                     SCH.sub.2                                                1186 2-O-t-C.sub.4 H.sub.9                                                                           SCH.sub.2                                                1187 3-O-t-C.sub.4 H.sub.9                                                                           SCH.sub.2                                                1188 4-O-t-C.sub.4 H.sub.9                                                                           SCH.sub.2                                                1189 2-OC.sub.6 H.sub.5                                                                              SCH.sub.2                                                1190 3-OC.sub.6 H.sub.5                                                                              SCH.sub.2                                                1191 4-OC.sub.6 H.sub.5                                                                              SCH.sub.2                                                1192 2-CF.sub.3       SCH.sub.2                                                1193 3-CF.sub.3       SCH.sub.2                                                1194 4-CF.sub.3       SCH.sub.2                                                1195 2-OCF.sub.3      SCH.sub.2                                                1196 3-OCF.sub.3      SCH.sub.2                                                1197 4-OCF.sub.3      SCH.sub.2                                                1198 3-OCH.sub.2 CHF.sub.2                                                                           SCH.sub.2                                                1199 3-OCF.sub.2 CHF.sub.2                                                                           SCH.sub.2                                                1200 3-OC.sub.2 F.sub.5                                                                              SCH.sub.2                                                1201 2-NO.sub.2       SCH.sub.2                                                1202 3-NO.sub.2       SCH.sub.2                                                1203 4-NO.sub.2       SCH.sub.2                                                1204 2-CN             SCH.sub.2                                                1205 3-CN             SCH.sub.2                                                1206 4-CN             SCH.sub.2                                                1207 2-CH.sub.3, 3-Cl SCH.sub.2                                                1208 2-CH.sub.3, 4-Cl SCH.sub.2                                                1209 2-CH.sub.3, 5-Cl SCH.sub.2                                                1210 2-CH.sub.3, 6-Cl SCH.sub.2                                                1211 2-CH.sub.3, 3-F  SCH.sub. 2                                               1212 2-CH.sub.3, 4-F  SCH.sub.2                                                1213 2-CH.sub.2, 5-F  SCH.sub.2                                                1214 2-CH.sub.3, 6-F  SCH.sub.2                                                1215 2-CH.sub.3, 3-Br SCH.sub.2                                                1216 2-CH.sub.3, 4-Br SCH.sub.2                                                1217 2-CH.sub.3, 5-Br SCH.sub.2                                                1218 2-CH.sub.3, 6-Br SCH.sub.2                                                1219 2-Cl, 3-CH.sub.3 SCH.sub.2                                                1220 2-Cl, 4-CH.sub.3 SCH.sub.2                                                1221 2-Cl, 5-CH.sub.3 SCH.sub.2                                                1222 2-F, 3-CH.sub.3  SCH.sub.2                                                1223 2-F, 4-CH.sub.3  SCH.sub.2                                                1224 2-F, 5-CH.sub.3  SCH.sub.2                                                1225 2-Br, 3-CH.sub.3 SCH.sub.2                                                1226 2-Br, 4-CH.sub.3 SCH.sub.2                                                1227 2-Br, 5-CH.sub.3 SCH.sub.2                                                1228 3-CH.sub.3, 4-Cl SCH.sub.2                                                1229 3-CH.sub.3, 5-Cl SCH.sub.2                                                1230 3-CH.sub.3, 4-F  SCH.sub.2                                                1231 3-CH.sub.3, 5-F  SCH.sub.2                                                1232 3-CH.sub.3, 4-Br SCH.sub.2                                                1233 3-CH.sub.3, 5-Br SCH.sub.2                                                1234 3-F, 4-CH.sub.3  SCH.sub.2                                                1235 3-Cl, 4-CH.sub.3 SCH.sub.2                                                1236 3-Br, 4-CH.sub.3 SCH.sub.2                                                1237 2-Cl, 4,5-(CH.sub.3).sub.2                                                                      SCH.sub.2                                                1238 2-Br, 4,5-(CH.sub.3).sub.2                                                                      SCH.sub.2                                                1239 2-Cl, 3,5-(CH.sub.3).sub.2                                                                      SCH.sub.2                                                1240 2-Br, 3,5-(CH.sub.3).sub.2                                                                      SCH.sub.2                                                1241 2,6-Cl.sub.2, 4-CH.sub.3                                                                        SCH.sub.2                                                1242 2,6-F.sub.2, 4-CH.sub.3                                                                         SCH.sub.2                                                1243 2,6-Br.sub.2, 4-CH.sub.3                                                                        SCH.sub.2                                                1244 2,4-Cl.sub.2, 6-CH.sub.3                                                                        SCH.sub.2                                                1245 2,4-F.sub.2, 6-CH.sub.3                                                                         SCH.sub.2                                                1246 2,4-Br.sub.2, 6-CH.sub.3                                                                        SCH.sub.2                                                1247 2,6-(CH.sub.3).sub.2, 4-F                                                                       SCH.sub.2                                                1248 2,6-(CH.sub.3).sub.2, 4-Cl                                                                      SCH.sub.2                                                1249 2,6-(CH.sub.3).sub.2, 4-Br                                                                      SCH.sub.2                                                1250 3,5-(CH.sub.3).sub.2, 4-F                                                                       SCH.sub.2                                                1251 3,5-(CH.sub.3).sub.2, 4-Cl                                                                      SCH.sub.2                                                1252 3,5-(CH.sub.3).sub.2, 4-Br                                                                      SCH.sub.2                                                1253 2,3,6-(CH.sub.3).sub.3, 4-F                                                                     SCH.sub.2                                                1254 2,3,6-(CH.sub.3).sub.3, 4-Cl                                                                    SCH.sub.2                                                1255 2,3,6-(CH.sub.3).sub.3, 4-Br                                                                    SCH.sub.2                                                1256 2,4-(CH.sub.3).sub.2, 6-F                                                                       SCH.sub.2                                                1257 2,4-(CH.sub.3).sub.2, 6-Cl                                                                      SCH.sub.2                                                1258 2,4-(CH.sub.3).sub.2, 6-Br                                                                      SCH.sub.2                                                1259 2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                                           SCH.sub.2                                                1260 2-CH.sub.3, 4-Cl, 5-i-C.sub.3 H.sub.7                                                           SCH.sub.2                                                1261 2-Cl, 3-i-C.sub.3 H.sub.7                                                                       SCH.sub.2                                                1262 2-Cl, 4-i-C.sub.3 H.sub.7                                                                       SCH.sub.2                                                1263 2-Cl, 4-NO.sub.2 SCH.sub.2                                                1264 2-NO.sub.2, 4-Cl SCH.sub.2                                                1265 2-OCH.sub.3, 5-NO.sub.2                                                                         SCH.sub.2                                                1266 2,4-Cl.sub.2, 5-NO.sub.2                                                                        SCH.sub.2                                                1267 2,4-Cl.sub.2, 6-NO.sub.2                                                                        SCH.sub.2                                                1268 2,6-Cl.sub.2, 4-NO.sub.2                                                                        SCH.sub.2                                                1269 2,6-Br.sub.2, 4-NO.sub.2                                                                        SCH.sub.2                                                1270 2,6-I.sub.2, 4-NO.sub.2                                                                         SCH.sub.2                                                1271 H                O                                                        1272 2-F              O                                                        1273 3-F              O                                                        1274 4-F              O                                                        1275 2,3-F.sub.2      O                                                        1276 2,4-F.sub.2      O                                                        1277 2,4,6-F.sub.3    O                                                        1278 2,3,4,5,6-F.sub.5                                                                               O                                                        1279 2-Cl             O                                                        1280 3-Cl             O                                                        1281 4-Cl             O                                                        1282 2,3-Cl.sub.2     O                                                        1283 2,4-Cl.sub.2     O                                                        1284 2,5-Cl.sub.2     O                                                        1285 2,6-Cl.sub.2     O                                                        1286 3,4-Cl.sub.2     O                                                        1287 3,5-Cl.sub.2     O                                                        1288 2,3,4-Cl.sub.3   O                                                        1289 2,3,5-Cl.sub.3   O                                                        1290 2,3,6-Cl.sub.3   O                                                        1291 2,4,5-Cl.sub.3   O                                                        1292 2,4,6-Cl.sub.3   O                                                        1293 3,4,5-Cl.sub.3   O                                                        1294 2,3,4,6-Cl.sub.4 O                                                        1295 2,3,5,6-Cl.sub.4 O                                                        1296 2,3,4,5,6-Cl.sub.5                                                                              O                                                        1297 2-Br             O                                                        1298 3-Br             O                                                        1299 4-Br             O                                                        1300 2,4-Br.sub.2     O                                                        1301 2,5-Br.sub.2     O                                                        1302 2,6-Br.sub.2     O                                                        1303 2,4,6-Br.sub.3   O                                                        1304 2,3,4,5,6-Br.sub.5                                                                              O                                                        1305 2-I              O                                                        1306 3-I              O                                                        1307 4-I              O                                                        1308 2,4-I.sub.2      O                                                        1309 2-Cl, 3-F        O                                                        1310 2-Cl, 4-F        O                                                        1311 2-Cl, 5-F        O                                                        1312 2-Cl, 6-F        O                                                        1313 2-Cl, 3-Br       O                                                        1314 2-Cl, 4-Br       O                                                        1315 2-Cl, 5-Br       O                                                        1316 2-Cl, 6-Br       O                                                        1317 2-Br, 3-Cl       O                                                        1318 2-Br, 4-Cl       O                                                        1319 2-Br, 5-Cl       O                                                        1320 2-Br, 3-F        O                                                        1321 2-Br, 4-F        O                                                        1322 2-Br, 5-F        O                                                        1323 2-Br, 6-F        O                                                        1324 2-F, 3-Cl        O                                                        1325 2-F, 4-Cl        O                                                        1326 2-F, 5-Cl        O                                                        1327 3-Cl, 4-F        O                                                        1328 3-Cl, 5-F        O                                                        1329 3-Cl, 4-Br       O                                                        1330 3-Cl, 5-Br       O                                                        1331 3-F, 4-Cl        O                                                        1332 3-F, 4-Br        O                                                        1333 3-Br, 4-Cl       O                                                        1334 3-Br, 4-F        O                                                        1335 2,6-Cl.sub.2, 4-Br                                                                              O                                                        1336 2-CH.sub.3       O                                                        1337 3-CH.sub.3       O                                                        1338 4-CH.sub.3       O                                                        1339 2,3-(CH.sub.3).sub.2                                                                            O                                                        1340 2,4-(CH.sub.3).sub.2                                                                            O                                                        1341 2,5-(CH.sub.3).sub.2                                                                            O                                                        1342 2,6-(CH.sub.3).sub.2                                                                            O                                                        1343 3,4-(CH.sub.3).sub.2                                                                            O                                                        1344 3,5-(CH.sub.3).sub.2                                                                            O                                                        1345 2,3,4-(CH.sub.3).sub.3                                                                          O                                                        1346 2,3,5-(CH.sub.3).sub.3                                                                          O                                                        1347 2,3,6-(CH.sub.3).sub.3                                                                          O                                                        1348 2,4,5-(CH.sub.3).sub.3                                                                          O                                                        1349 2,4,6-(CH.sub.3).sub.3                                                                          O                                                        1350 3,4,5-(CH.sub.3).sub.3                                                                          O                                                        1351 2,3,4,6-(CH.sub.3).sub.4                                                                        O                                                        1352 2,3,5,6-(CH.sub.3).sub.4                                                                        O                                                        1353 2,3,4,5,6-(CH.sub.3).sub. 5                                                                     O                                                        1354 2-C.sub.2 H.sub.5                                                                               O                                                        1355 3-C.sub.2 H.sub.5                                                                               O                                                        1356 4-C.sub.2 H.sub.5                                                                               O                                                        1357 2,4-(C.sub.2 H.sub.5).sub.2                                                                     O                                                        1358 2,6-(C.sub.2 H.sub.5).sub.2                                                                     O                                                        1359 3,5-(C.sub.2 H.sub.5).sub.2                                                                     O                                                        1360 2,4,6-(C.sub.2 H.sub.5).sub.3                                                                   O                                                        1361 2-n-C.sub.3 H.sub.7                                                                             O                                                        1362 3-n-C.sub.3 H.sub.7                                                                             O                                                        1363 4-n-C.sub.3 H.sub.7                                                                             O                                                        1364 2-i-C.sub.3 H.sub.7                                                                             O                                                        1365 3-i-C.sub.3 H.sub.7                                                                             O                                                        1366 4-i-C.sub.3 H.sub.7                                                                             O                                                        1367 2,4-(i-C.sub.3 H.sub.7).sub.2                                                                   O                                                        1368 2,6-(i-C.sub.3 H.sub.7).sub.2                                                                   O                                                        1369 3,5-(i-C.sub.3 H.sub.7).sub.2                                                                   O                                                        1370 2,4,6-(i-C.sub.3 H.sub.7).sub.2                                                                 O                                                        1371 2-s-C.sub.4 H.sub.9                                                                             O                                                        1372 3-s-C.sub.4 H.sub.9                                                                             O                                                        1373 4-s-C.sub.4 H.sub.9                                                                             O                                                        1374 2-t-C.sub.4 H.sub.9                                                                             O                                                        1375 3-t-C.sub.4 H.sub.9                                                                             O                                                        1376 4-t-C.sub.4 H.sub.9                                                                             O                                                        1377 2,3-(t-C.sub.4 H.sub.9).sub.2                                                                   O                                                        1378 2,4-(t-C.sub.4 H.sub.9).sub.2                                                                   O                                                        1379 2,5-(t-C.sub.4 H.sub.9).sub.2                                                                   O                                                        1380 2,6-(t-C.sub.4 H.sub.9).sub.2                                                                   O                                                        1381 3,5-(t-C.sub.4 H.sub.9).sub.2                                                                   O                                                        1382 2,4,6-(t-C.sub.4 H.sub. 9).sub.3                                                                O                                                        1383 4-n-C.sub.9 H.sub.19                                                                            O                                                        1384 4-n-C.sub.12 H.sub.25                                                                           O                                                        1385 3-n-C.sub.15 H.sub.31                                                                           O                                                        1386 4-(1,1,3,3,-tetramethylbutyl)                                                                   O                                                        1387 4-(1,1,3,-trimethybutyl)                                                                        O                                                        1388 2-t-C.sub.4 H.sub.9, 4-CH.sub.3                                                                 O                                                        1389 2-t-C.sub.4 H.sub.9, 5-CH.sub.3                                                                 O                                                        1390 2,6-(t-C.sub.4 H.sub.9).sub.2, 4-CH.sub.3                                                       O                                                        1391 2-CH.sub.3, 4-t-C.sub.4 H.sub.9                                                                 O                                                        1392 2-CH.sub.3, 6-t-C.sub.4 H.sub.9                                                                 O                                                        1393 2-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 O                                                        1394 2-CH.sub.3, 5-i-C.sub.3 H.sub.7                                                                 O                                                        1395 3-CH.sub.3, 4-i-C.sub.3 H.sub.7                                                                 O                                                        1396 2-i-C.sub.3 H.sub.7, 5-CH.sub.3                                                                 O                                                        1397 2,4-(t-C.sub.4 H.sub.9).sub.2, 6-i-C.sub.3 H.sub.7                                              O                                                        1398 2-C.sub.3 H.sub.5 (= allyl)                                                                     O                                                        1399 3-C.sub.3 H.sub.5                                                                               O                                                        1400 4-C.sub.3 H.sub.5                                                                               O                                                        1401 2-C.sub.3 H.sub.5, 6-CH.sub.3                                                                   O                                                        1402 2-cyclo-C.sub.6 H.sub.11                                                                        O                                                        1403 3-cyclo-C.sub.6 H.sub.11                                                                        O                                                        1404 4-cyclo-C.sub.6 H.sub.11                                                                        O                                                        1405 2,4-(cyclo-C.sub.6 H.sub.11).sub.2, 6-CH.sub.3                                                  O                                                        1406 2-CH.sub.3, 4-cyclo-C.sub.6 H.sub.11                                                            O                                                        1407 2-CH.sub.3, 4-(1,1,3,3-tetramethylbutyl)                                                        O                                                        1408 2-CH.sub.2 C.sub.6 H.sub.5                                                                      O                                                        1409 3-CH.sub.2 C.sub.6 H.sub.5                                                                      O                                                        1410 4-CH.sub.2 C.sub.6 H.sub.5                                                                      O                                                        1411 2-CH.sub.2 C.sub.6 H.sub.5, 4-CH.sub.3                                                          O                                                        1412 2-CH.sub.3, 4-CH.sub.2 C.sub.6 H.sub.5                                                          O                                                        1413 2-C.sub.6 H.sub.5                                                                               O                                                        1414 3-C.sub.6 H.sub.5                                                                               O                                                        1415 4-C.sub.6 H.sub.5                                                                               O                                                        1416 4-(2-i-C.sub.3 H.sub.7C.sub.6 H.sub.4)                                                          O                                                        1417 4-C.sub.6 H.sub.5, 2,6-(CH.sub.3).sub.2                                                         O                                                        1418 2-Cl, 4-C.sub.6 H.sub.5                                                                         O                                                        1419 2-Br, 4-C.sub.6 H.sub.5                                                                         O                                                        1420 2-C.sub.6 H.sub.5, 4-Cl                                                                         O                                                        1421 2-C.sub.6 H.sub.5, 4-Br                                                                         O                                                        1422 2-CH.sub.2 C.sub.6 H.sub.5, 4-Cl                                                                O                                                        1423 2-CH.sub.2 C.sub.6 H.sub.5, 4-Br                                                                O                                                        1424 2-Cl, 4-CH.sub.2 C.sub.6 H.sub.5                                                                O                                                        1425 2-Br, 4-CH.sub.2 C.sub.6 H.sub.5                                                                O                                                        1426 2-cyclo-C.sub.6 H.sub.11, 4-Cl                                                                  O                                                        1427 2-cyclo-C.sub.6 H.sub.11, 4-Br                                                                  O                                                        1428 2-Cl, 4-cyclo-C.sub.6 H.sub.11                                                                  O                                                        1429 2-Br, 4-cyclo-C.sub.6 H.sub.11                                                                  O                                                        1430 2-OCH.sub.3      O                                                        1431 3-OCH.sub.3      O                                                        1432 4-OCH.sub.3      O                                                        1433 2,4-(OCH.sub.3).sub.2                                                                           O                                                        1434 2-OC.sub.2 H.sub.5                                                                              O                                                        1435 3-OC.sub.2 H.sub.5                                                                              O                                                        1436 4-OC.sub.2 H.sub.5                                                                              O                                                        1437 2-OCH.sub.2 C.sub.6 H.sub.5                                                                     O                                                        1438 3-OCH.sub.2 C.sub.6 H.sub.5                                                                     O                                                        1439 4-OCH.sub.2 C.sub.6 H.sub.5                                                                     O                                                        1440 2-O-t-C.sub.4 H.sub.9                                                                           O                                                        1441 3-O-t-C.sub.4 H.sub.9                                                                           O                                                        1442 4-O-t-C.sub.4 H.sub.9                                                                           O                                                        1443 2-OC.sub.6 H.sub.5                                                                              O                                                        1444 3-OC.sub.6 H.sub.5                                                                              O                                                        1445 4-OC.sub.6 H.sub.5                                                                              O                                                        1446 2-CF.sub.3       O                                                        1447 3-CF.sub.3       O                                                        1448 4-CF.sub.3       O                                                        1449 2-OCF.sub.3      O                                                        1450 3-OCF.sub.3      O                                                        1451 4-OCF.sub.3      O                                                        1452 3-OCH.sub.2 CHF.sub.2                                                                           O                                                        1453 3-OCF.sub.2 CHF.sub.2                                                                           O                                                        1454 3-OC.sub.2 H.sub.5                                                                              O                                                        1455 2-NO.sub.2       O                                                        1456 3-NO.sub.2       O                                                        1457 4-NO.sub.2       O                                                        1458 2-CN             O                                                        1459 3-CN             O                                                        1460 4-CN             O                                                        1461 2-CH.sub.3, 3-Cl O                                                        1462 2-CH.sub.3, 4-Cl O                                                        1463 2-CH.sub.3, 5-Cl O                                                        1464 2-CH.sub.3, 6-Cl O                                                        1465 2-CH.sub.3, 3-F  O                                                        1466 2-CH.sub.3, 4-F  O                                                        1467 2-CH.sub.3, 5-F  O                                                        1468 2-CH.sub.3, 6-F  O                                                        1469 2-CH.sub.3, 3-Br O                                                        1470 2-CH.sub.3, 4-Br O                                                        1471 2-CH.sub.3, 5-Br O                                                        1472 2-CH.sub.3, 6-Br O                                                        1473 2-Cl, 3-CH.sub.3 O                                                        1474 2-Cl, 4-CH.sub.3 O                                                        1475 2-Cl, 5-CH.sub.3 O                                                        1476 2-F, 3-CH.sub.3  O                                                        1477 2-F, 4-CH.sub.3  O                                                        1478 2-F, 5-CH.sub.3  O                                                        1479 2-Br, 3-CH.sub.3 O                                                        1480 2-Br, 4-CH.sub.3 O                                                        1481 2-Br, 5-CH.sub.3 O                                                        1482 3-CH.sub.3, 4-Cl O                                                        1483 3-CH.sub.3, 5-Cl O                                                        1484 3-CH.sub.3, 4-F  O                                                        1485 3-CH.sub.3, 5-F  O                                                        1486 3-CH.sub.3, 4-Br O                                                        1487 3-CH.sub.3, 5-Br O                                                        1488 3-F, 4-CH.sub.3  O                                                        1489 3-Cl, 4-CH.sub.3 O                                                        1490 3-Br, 4-CH.sub.3 O                                                        1491 2-Cl, 4,5-(CH.sub.3).sub.2                                                                      O                                                        1492 2-Br, 4,5-(CH.sub.3).sub.2                                                                      O                                                        1493 2-Cl, 3,5-(CH.sub.3).sub.2                                                                      O                                                        1494 2-Br, 3,5-(CH.sub.3).sub.2                                                                      O                                                        1495 2,6-Cl.sub.2, 4-CH.sub.3                                                                        O                                                        1496 2,6-F.sub.2, 4-CH.sub.3                                                                         O                                                        1497 2,6-Br.sub.2, 4-CH.sub.3                                                                        O                                                        1498 2,4-Cl.sub.2, 6-CH.sub.3                                                                        O                                                        1499 2,4-F.sub.2, 6-CH.sub.3                                                                         O                                                        1500 2,4-Br.sub.2, 6-CH.sub.3                                                                        O                                                        1501 2,6-(CH.sub.3).sub.2, 4-F                                                                       O                                                        1502 2,6-(CH.sub.3).sub.2, 4-Cl                                                                      O                                                        1503 2,6-(CH.sub.3).sub. 2, 4-Br                                                                     O                                                        1504 3,5-(CH.sub.3).sub.2, 4-F                                                                       O                                                        1505 3,5-(CH.sub.3).sub.2, 4-Cl                                                                      O                                                        1506 3,5-(CH.sub.3).sub.2, 4-Br                                                                      O                                                        1507 2,3,6-(CH.sub.3).sub.3, 4-F                                                                     O                                                        1508 2,3,6-(CH.sub.3).sub.3, 4-Cl                                                                    O                                                        1509 2,3,6-(CH.sub.3).sub.3, 4-Br                                                                    O                                                        1510 2,4-(CH.sub.3).sub.2, 6-F                                                                       O                                                        1511 2,4-(CH.sub.3).sub.2, 6-Cl                                                                      O                                                        1512 2,4-(CH.sub.3).sub.2, 6-Br                                                                      O                                                        1513 2-i-C.sub.3 H.sub.7, 4-Cl, 5-CH.sub.3                                                           O                                                        1514 2-CH.sub.3, 4-Cl, 5-i-C.sub.3 H.sub.7                                                           O                                                        1515 2-Cl, 3-i-C.sub.3 H.sub.7                                                                       O                                                        1516 2-Cl, 4-i-C.sub.3 H.sub.7                                                                       O                                                        1517 2-Cl, 4-NO.sub.2 O                                                        1518 2-NO.sub.2, 4-Cl O                                                        1519 2-OCH.sub.3, 5-NO.sub.2                                                                         O                                                        1520 2,4-Cl.sub.2, 5-NO.sub.2                                                                        O                                                        1521 2,4-Cl.sub.2, 6-NO.sub.2                                                                        O                                                        1522 2,6-Cl.sub.2, 4-NO.sub.2                                                                        O                                                        1523 2,6-Br.sub.2, 4-NO.sub.2                                                                        O                                                        1524 2,6-I.sub.2, 4-NO.sub.2                                                                         O                                                        1525 *1)              OCH.sub.2                                                1526 *2)              OCH.sub.2                                                1527 *1)              CH.sub.2 O                                               1528 *2)              CH.sub.2 O                                               __________________________________________________________________________      ##STR14##                                                                      ##STR15##                                                                

Generally speaking, the novel compounds are extremely effective on a broad spectrum of phytopathogenic fungi, in particular those from the Ascomycetes and Basidiomycetes classes. Some of them have a systemic action and can be used as foliar and soil fungicides.

The fungicidal compounds are of particular interest for controlling a large number of fungi in various crops or their seeds, especially wheat, rye, barley, oats, rice, Indian corn, lawns, cotton, soybeans, coffee, sugar cane, fruit and ornamentals in horticulture and viticulture, and in vegetables such as cucumbers, beans and cucurbits.

The novel compounds are particularly useful for controlling the following plant diseases:

Erysiphe graminis in cereals,

Erysiphe cichoracearum and Sphaerotheca fuliginea in cucurbits,

Podosphaera leucotricha in apples,

Uncinula necator in vines,

Puccinia species in cereals,

Rhizoctonia species in cotton and lawns,

Ustilago species in cereals and sugar cane,

Venturia inaequalis (scab) in apples,

Helminthosporium species in cereals,

Septoria nodorum in wheat,

Botrytis cinerea (gray mold) in strawberries and grapes,

Cercospora arachidicola in groundnuts,

Pseudocercosporella herpotrichoides in wheat and barley,

Pyricularia oryzae in rice,

Phytophthora infestans in potatoes and tomatoes,

Fusarium and Verticillium species in various plants,

Plasmopara viticola in grapes,

Alternaria species in vegetables and fruit.

The compounds are applied by spraying or dusting the plants with the active ingredients, or treating the seeds of the plants with the active ingredients. They may be applied before or after infection of the plants or seeds by the fungi. Either the fungi themselves, or the plants, seeds, materials or soil to be protected against fungal attack are treated with a fungicidally effective amount of the active ingredient.

The novel substances can be converted into conventional formulations such as solutions, emulsions, suspensions, dusts, powders, pastes and granules. The application forms depend entirely on the purposes for which they are intended; they should at all events ensure a fine and uniform distribution of the active ingredient. The formulations are produced in known manner, for example by extending the active ingredient with solvents and/or carriers, with or without the use of emulsifiers and dispersants; if water is used as solvent, it is also possible to employ other organic solvents as auxiliary solvents. Suitable auxiliaries for this purpose are solvents such as aromatics (e.g., xylene), chlorinated aromatics (e.g., chlorobenzenes), paraffins (e.g., crude oil fractions), alcohols (e.g., methanol, butanol), ketones (e.g., cyclohexanone), amines (e.g., ethanolamine, dimethylformamide), and water; carriers such as ground natural minerals (e.g., kaolins, aluminas, talc and chalk) and ground synthetic minerals (e.g., highly disperse silica and silicates); emulsifiers such as nonionic and anionic emulsifiers (e.g., polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates); and dispersants such as lignin-sulfite waste liquors and methylcellulose.

The fungicidal agents generally contain from 0.1 to 95, and preferably from 0.5 to 90, wt. % of active ingredient. The application rates are from 0.02 to 3 kg or more of active ingredient per hectare, depending on the type of effect desired. The novel compounds may also be used for protecting materials (wood), for example against Paecilomyces variotti.

When the active ingredients are used for treating seed, amounts of from 0.001 to 50, and preferably from 0.01 to 10, g per kg of seed are usually employed.

The agents and the ready-to-use formulations prepared from them, such as solutions, emulsions, suspensions, powders, dusts, pastes and granules, are applied in conventional manner, for example by spraying, atomizing, dusting, scattering, dressing or watering.

Examples of formulations are given below.

I. 90 parts by weight of compound no. 4 is mixed with 10 parts by weight of N-methyl-α-pyrrolidone. A mixture is obtained which is suitable for application in the form of very fine drops.

II. 20 parts by weight of compound no. 11 is dissolved in a mixture consisting of 80 parts by weight of xylene, 10 parts by weight of the adduct of 8 to 10 moles of ethylene oxide and 1 mole of oleic acid N-monoethanolamide, 5 parts by weight of the calcium salt of dodecylbenzenesulfonic acid, and 5 parts by weight of the adduct of 40 moles of ethylene oxide and 1 mole of castor oil. By pouring the solution into water and uniformly distributing it therein, an aqueous dispersion is obtained.

III. 20 parts by weight of compound no. 66 is dissolved in a mixture consisting of 40 parts by weight of cyclohexanone, 30 parts by weight of isobutanol, 20 parts by weight of the adduct of 40 moles of ethylene oxide and 1 mole of castor oil. By pouring the solution into water and finely distributing it therein, an aqueous dispersion is obtained.

IV. 20 parts by weight of compound no. 4 is dissolved in a mixture consisting of 25 parts by weight of cyclohexanol, 65 parts by weight of a mineral oil fraction having a boiling point between 210° and 280° C., and 10 parts by weight of the adduct of 40 moles of ethylene oxide and 1 mole of castor oil. By pouring the solution into water and uniformly distributing it therein, an aqueous dispersion is obtained.

V. 80 parts by weight of compound no. 11 is well mixed with 3 parts by weight of the sodium salt of diisobutylnaphthalene-α-sulfonic acid, 10 parts by weight of the sodium salt of a lignin-sulfonic acid obtained from a sulfite waste liquor, and 7 parts by weight of powdered silica gel, and triturated in a hammer mill. By uniformly distributing the mixture in water, a spray liquor is obtained.

VI. 3 parts by weight of compound no. 66 is intimately mixed with 97 parts by weight of particulate kaolin. A dust is obtained containing 3% by weight of the active ingredient.

VII. 30 parts by weight of compound no. 4 is intimately mixed with a mixture consisting of 92 parts by weight of powdered silica gel and 8 parts by weight of paraffin oil which has been sprayed onto the surface of this silica gel. A formulation of the active ingredient is obtained having good adherence.

VIII. 40 parts by weight of compound no. 11 is intimately mixed with 10 parts by weight of the sodium salt of a phenolsulfonic acid-urea-formaldehyde condensate, 2 parts of silica gel and 48 parts of water to give a stable aqueous dispersion. Dilution in water gives an aqueous dispersion.

IX. 20 parts by weight of compound no. 66 is intimately mixed with 2 parts by weight of the calcium salt of dodecylbenzenesulfonic acid, 8 parts by weight of a fatty alcohol polyglycol ether, 2 parts by weight of the sodium salt of a phenolsulfonic acid-urea-formaldehyde condensate and 68 parts by weight of a paraffinic mineral oil. A stable oil dispersion is obtained.

In these application forms, the agents according to the invention may also be present together with other active ingredients, for example herbicides, insecticides, growth regulators, and fungicides, and may furthermore be mixed and applied together with fertilizers. Admixture with other fungicides frequently results in an increase in the fungicidal spectrum.

USE EXAMPLE

The active ingredient 2-(2-methylbenzyloxy)-phenylglyoxylic acid methyl ester-O-methyloxime (A) disclosed in EP 253,213 was used for comparison purposes.

ACTION ON PYRENOPHORA TERES

Barley seedlings of the "Igri" variety were sprayed to runoff at the two-leaf stage with aqueous suspensions consisting (dry basis) of 80% of active ingredient and 20% of emulsifier. After 24 hours the plants were inoculated with a spore suspension of the fungus Pyrenophora teres, and set up for 48 hours in a high-humidity climatic cabinet at 18° C. The plants were then cultivated for a further 5 days in the greenhouse at 20° to 22° C. and a relative humidity of 70° C. The extent of fungus spread was then assessed.

The results shows that active ingredients 4, 11 and 66, applied as 0.05 wt % spray liquors, have a better fungicidal action (90%) than prior art comparative agent A (60%). 

We claim:
 1. A compound of the formula I ##STR16## where the radicals R (m=1 to 5) are identical or different and are each hydrogen, halogen, cyano, nitro, C₁ -C₁₅ -alkyl, C₃ -C₆ -cycloalkyl, C₃ -C₆ -alkenyl, C₁ -C₄ -alkoxy, C₁ -C₂ -haloalkyl, C₁ -C₂ -haloalkoxy, phenyl, C₁ -C₄ -alkylphenyl, halophenyl, phenoxy, C₁ -C₄ -alkylphenoxy, halophenoxy, benzyl, halobenzyl, benzyloxy, halobenzyloxy, or C₁ -C₄ -alkylbenzyloxy or the group ##STR17## is α-naphthyl or β-naphthyl, and X is methyleneoxy, oxymethylene, ethylene, ethenylene, thiomethylene or oxygen.
 2. A process for combating fungi, wherein the fungi, or the materials, plants, seed or soil threatened by fungus attack are treated with a fungicidally effective amount of a compound of the formula I ##STR18## where the radicals R (m=1 to 5) are identical or different and are each hydrogen, halogen, cyano, nitro, C₁ -C₁₅ -alkyl, C₃ -C₆ -cycloalkyl, C₃ -C₆ -alkenyl, C₁ -C₄ -alkoxy, C₁ -C₂ -haloalkyl, C₁ -C₂ -haloalkoxy, phenyl, C₁ -C₄ -alkylphenyl, halophenyl, phenoxy, C₁ -C₄ -alkylphenoxy, halophenoxy, benzyl, halobenzyl, benzyloxy, halobenzyloxy, or C₁ -C₄ -alkylbenzyloxy or the group ##STR19## is α-naphthyl or β-naphthyl, and X is methyleneoxy, oxymethylene, ethylene, ethenylene, thiomethylene or oxygen.
 3. A fungicide containing an inert carrier and a fungicidally effective amount of a compound of the formula I ##STR20## where the radicals R (m=1 to 5) are identical or different and are each hydrogen, halogen, cyano, nitro, C₁ -C₁₅ -alkyl, C₃ -C₆ -cycloalkyl, C₃ -C₆ -alkenyl, C₁ -C₄ -alkoxy, C₁ -C₂ -haloalkyl, C₁ -C₂ -haloalkoxy, C₁ -C₄ -alkylphenyl, halophenyl, phenoxy, C₁ -C₄ -alkylphenoxy, halophenoxy, benzyl, halobenzyl, benzyloxy, halobenzyloxy, or C₁ -C₄ -alkylbenzyloxy or the group ##STR21## is α-naphthyl or β-naphthyl, and X is methyleneoxy, oxymethylene, ethylene, ethenylene, thiomethylene or oxygen.
 4. A compound of the formula I as set forth in claim 1, where R_(m) is 2-methyl and X is methyleneoxy.
 5. A compound of the formula I as set forth in claim 1, where R_(m) is 4-fluoro and X is methyleneoxy.
 6. A compound of the formula I as set forth in claim 1, where R_(m) is 4-chloro and X is methyleneoxy.
 7. A compound of claim 1, wherein R_(m) is 2-bromo and X is methyleneoxy.
 8. A compound of claim 1, wherein R_(m) is 3-bromo and X is methyleneoxy. 